BEHAVIOR OF PRUSSIAN BLUE DURING ITS INTERACTION WITH OZONE

被引：23
|
作者：
REGUERA, E
FERNANDEZBERTRAN, J
DIAZ, C
MOLERIO, J
机构：
[1] Centro Nacional de Investigaciones Cientificas, Havana
来源：
HYPERFINE INTERACTIONS | 1992年 / 73卷 / 3-4期
关键词：
D O I：
10.1007/BF02418603
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The interaction of ozone with Prussian Blue has been studied by Mossbauer, infrared and XRD techniques. All spectral results reveal a reversible conversion of ferrocyanide to ferricyanide with preservation of the crystal skeleton. Ferric ferricyanide obtained by ozonization of ferric ferrocyanide has Mossbauer parameters different to those of an ordered Prussian Brown, which has been attributed to secondary reaction products located at the zeolite voids of the former compound.
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收藏
页码：285 / 294
页数：10
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