CHARGE-TRANSFER COMPLEXES OF TERTIARY AROMATIC-AMINES WITH TETRACYANOETHYLENE

被引：0

作者：

SERSEN, F ^{[1
]}

LACKO, I ^{[1
]}

DEVINSKY, F ^{[1
]}

机构：

[1] COMENIUS UNIV BRATISLAVA,FAC PHARM,DEPT CHEM THEORY DRUGS,BRATISLAVA 83232,SLOVAKIA

来源：

CHEMICAL PAPERS-CHEMICKE ZVESTI | 1995年 / 49卷 / 01期

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D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tertiary aromatic amines N,N-diethylaniline, N-methyl-N,N-diphenylamine, and triphenylamine form charge-transfer complexes with tetracyanoethylene in solutions, which may subsequently undergo further chemical reactions. Using UV VIS and EPR spectroscopies it has been found that for the stability of the complex the delocalization of nonbonding nitrogen electrons, i.e. the electron density in the para position on the benzene rings of studied amines is important. On the other hand, the values of the ionization potentials are important mainly for the formation of charge-transfer complexes.

引用

页码：28 / 31

页数：4

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