A NEW, HIGHLY EFFICIENT SYNTHESIS OF CONJUGATED NITROCYCLOALKENES

被引：21

作者：

BALLINI, R

PALESTINI, C

机构：

[1] Dipartimento di Scienze Chimiche dell'Università, I-62032 Camerino

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(00)77291-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium borohydride reduction of alpha-nitrocycloalkanones and successive dehydration of the obtained beta-nitroalkanols, by acetylation and dehydroacetylation with basic alumina/DMAP, in refluxing dichloromethane, affords, in one-pot procedure, conjugated nitrocycloalkenes.

引用

页码：5731 / 5734

页数：4

共 30 条

[11] ALPHA-NITRO KETONES .6. SYNTHESIS AND CONFORMATION OF 2-METHYL-2-NITRO-CYCLOHEXANONE, CIS-6-METHYL-2-NITROCYCLOHEXANONE AND TRANS-6-METHYL-2-NITRO-, AND CIS-2,6-DIMETHYL-2-NITROCYCLOHEXANONE AND TRANS-2,6-DIMETHYL-2-NITROCYCLOHEXANONE
DAMPAWAN, P
ZAJAC, WW
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (07) : 1176 - 1181
[12] INTERMOLECULAR AND INTRAMOLECULAR [4+2] CYCLOADDITIONS OF NITROALKENES WITH OLEFINS - 2-NITROSTYRENES
DENMARK, SE
KESLER, BS
MOON, YC
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (18) : 4912 - 4924
[13] FISHER RH, 1981, SYNTHESIS-STUTTGART, P261
[14] HAYAMA T, 1982, TETRAHEDRON LETT, V23, P4733, DOI 10.1016/S0040-4039(00)85699-3
[15] EFFICIENT FUNCTIONAL-GROUP TRANSFORMATIONS ON A CYCLIC NITROALKENE SYSTEM
HWU, JR
WANG, N
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (06) : 427 - 428
[16] SYNTHESES AND SELECTED REDUCTIONS OF CONJUGATED NITROALKENES - A REVIEW
KABALKA, GW
VARMA, RS
[J]. ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1987, 19 (4-5) : 283 - 328
[17] KNOCHEL P, 1982, SYNTHESIS-STUTTGART, P1017
[18] SYNTHESIS AND REACTIONS OF SUBSTITUTED NITRO-ALLYLATING REAGENTS
KNOCHEL, P
SEEBACH, D
[J]. TETRAHEDRON LETTERS, 1982, 23 (38) : 3897 - 3900
[19] A CONVENIENT PREPARATION OF CONJUGATED NITRO OLEFINS BY ELECTROCHEMICAL METHOD
KUNAI, A
YANAGI, Y
SASAKI, K
[J]. TETRAHEDRON LETTERS, 1983, 24 (41) : 4443 - 4444
[20] NEW METHOD FOR DEHYDRATION OF NITRO ALCOHOLS
MELTON, J
MCMURRY, JE
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (14) : 2138 - 2139

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