ACCELERATION IN WATER OF THE BAYLIS-HILLMAN REACTION

被引：84

作者：

AUGE, J ^{[1
]}

LUBIN, N ^{[1
]}

LUBINEAU, A ^{[1
]}

机构：

[1] UNIV PARIS 11,CNRS,CHIM ORGAN MULTIFONCT LAB,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 43期

关键词：

D O I：

10.1016/0040-4039(94)80018-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

DABCO-catalyzed coupling reaction of benzaldehyde with acrylonitrile was greatly accelerated in water compared to usual organic solvents. The reaction was even more accelerated by adding lithium or sodium iodide in the aqueous medium. Other structured solvents also enhanced the reaction, but to a smaller extent.

引用

页码：7947 / 7948

页数：2