ASYMMETRIC DIELS-ALDER REACTIONS WITH CHIRAL 1-AZADIENES

被引：66
|
作者：
BEAUDEGNIES, R [1 ]
GHOSEZ, L [1 ]
机构：
[1] UNIV CATHOLIQUE LOUVAIN,CHIM ORGAN SYNTHESE LAB,B-1348 LOUVAIN,BELGIUM
来源：
TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 04期
关键词：
ASYMMETRIC CYCLOADDITIONS; 1-AZADIENES; PIPERIDINES;
D O I：
10.1016/0957-4166(94)80017-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chiral 1-azadienes 1 derived from alpha,beta-unsaturated aldehydes and Enders' hydrazines cycloadd to cyclic dienophiles with high facial selectivities. The adducts can be readily converted into enantiomerically pure piperidine derivatives.
引用
收藏
页码：557 / 560
页数：4
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