Applications of laser spectroscopy to triplet metal-to-ligand charge transfer transitions

被引：3
|
作者：
Riesen, H
Krausz, E
机构：
[1] Australian Natl Univ, Canberra
来源：
JOURNAL OF LUMINESCENCE | 1995年 / 66-7卷 / 1-6期
基金：
澳大利亚研究理事会;
关键词：
D O I：
10.1016/0022-2313(95)00198-0
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
A wide range of experiments has led to a clear understanding of the lowest-excited triplet metal-to-ligand charge transfer ((3)MLCT) transitions in metal-di-imine complexes embedded in crystalline hosts. In [Ru(di-imine)(3)](2+) complexes the static diagonal disorder in the metal-ligand subunit energies is substantially larger than the effective excitation exchange interaction beta leading invariably to localised lowest excited states.
引用
收藏
页码：496 / 505
页数：10
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