PHYSICAL GELS FROM PVC - DYNAMIC PROPERTIES OF DILUTE-SOLUTIONS

被引：21
|
作者：
CANDAU, SJ [1 ]
DORMOY, Y [1 ]
MUTIN, PH [1 ]
DEBEAUVAIS, F [1 ]
GUENET, JM [1 ]
机构：
[1] UNIV STRASBOURG 1,CNRS,ECOLE APPLICAT HAUTS POLYMERS,CTR RECH MACROMOLEC,INST CHARLES,F-67083 STRASBOURG,FRANCE
来源：
POLYMER | 1987年 / 28卷 / 08期
关键词：
DIFFUSION; -; GELS; POLYMERS; Viscosity;
D O I：
10.1016/0032-3861(87)90448-4
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In an effort to gain information on the gelation mechanism of poly(vinyl chloride) (PVC) in diethyl malonate, investigations of dilute PVC solutions were made using transient electric birefringence, flow birefringence, dynamic light scattering and viscometry. The dynamical structure factor obtained from the cumulant analysis of the autocorrelation function of scattered field exhibits an anomalous K dependence which can be attributed to an intramolecular effect. Measurements of intrinsic viscosity and rotational diffusion coefficient provide information on the internal structure of the aggregates formed by quenching dilute PVC solutions.
引用
收藏
页码：1334 / 1340
页数：7
相关论文
共 50 条
  • [31] Frozen-in magnetic order in uniaxial magnetic gels: Preparation and physical properties
    Collin, D
    Auernhammer, GK
    Gavat, O
    Martinoty, P
    Brand, HR
    MACROMOLECULAR RAPID COMMUNICATIONS, 2003, 24 (12) : 737 - 741
  • [32] Transport properties in dilute UN(X) solid solutions (X = Xe, Kr)
    Claisse, Antoine
    Schuler, Thomas
    Lopes, Denise Adorno
    Olsson, Par
    PHYSICAL REVIEW B, 2016, 94 (17)
  • [33] Dynamic covalent gels assembled from small molecules:from discrete gelators to dynamic covalent polymers
    Jian-Yong Zhang
    Li-Hua Zeng
    Juan Feng
    Chinese Chemical Letters, 2017, 28 (02) : 168 - 183
  • [34] Combined microscopic and dynamic rheological methods for studying the structural breakdown properties of whey protein gels and emulsion filled gels
    Abhyankar, Aniket R.
    Mulvihill, Daniel M.
    Auty, Mark A. E.
    FOOD HYDROCOLLOIDS, 2011, 25 (03) : 275 - 282
  • [35] Dynamic covalent gels assembled from small molecules: from discrete gelators to dynamic covalent polymers
    Zhang, Jian-Yong
    Zeng, Li-Hua
    Feng, Juan
    CHINESE CHEMICAL LETTERS, 2017, 28 (02) : 168 - 183
  • [36] Effect of additives on volatility of aroma compounds from dilute aqueous solutions
    Barankova, Eva
    Dohnal, Vladimir
    FLUID PHASE EQUILIBRIA, 2016, 407 : 217 - 223
  • [37] Adsorption from a mixture of thermodynamically compatible polymers in dilute and semidilute solutions
    Lipatov, Yu.S.
    Chornaya, V.N.
    Todosiichuk, T.T.
    Khramova, T.S.
    Polymer science USSR, 1990, 32 (12): : 2517 - 2524
  • [38] Concentration effects on turbulence in dilute polymer solutions far from walls
    Quitry, Alexandre de Chaumont
    Ouellette, Nicholas T.
    PHYSICAL REVIEW E, 2016, 93 (06)
  • [39] Relationship between Flow Properties and Elastic Stresses of Dilute and Ultra-Dilute Polymer Solutions Passing through Small Apertures
    Ushida, Akiomi
    Sato, Taisuke
    Narumi, Takatsune
    Hasegawa, Tomiichi
    NIHON REOROJI GAKKAISHI, 2021, 49 (01) : 29 - 39
  • [40] Study on the interfacial properties of viscous capillary flow of dilute acetic acid solutions of chitosan
    Cai, Zhengchun
    Dai, Jie
    Yang, Hu
    Cheng, Rongshi
    CARBOHYDRATE POLYMERS, 2009, 78 (03) : 488 - 491
12345