MULTIPORPHYRIN [2]-ROTAXANES AND [3]-CATENATES VIA COPPER(I)-TEMPLATED SYNTHESIS

被引：0

作者：

CHAMBRON, JC

HEITZ, V

SAUVAGE, JP

机构：

来源：

BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE | 1995年 / 132卷 / 03期

关键词：

ROTAXANE; CATENATE; PORPHYRIN; TEMPLATE SYNTHESIS;

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Condensation of dipyrrylmethane units onto a copper(I) complex, in which a diphenylphenanthroline ligand bearing aldehyde functions is threaded into a phenanthroline-containing macrocycle, afforded a copper(I)-complexed bisporphyrin-stoppered [2]-rotaxane or a bis-porphyrin-bridged [3]-catenate, depending on whether a second, aromatic aldehyde was added to the reaction mixture or not. The isolated yields were 18 and 5% respectively. In a separate experiment, a macrocyclic compound identical to the central ring of the [3]-catenate (46-membered ring) has also been synthesized in 28% yield.

引用

页码：340 / 347

页数：8

共 29 条

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