INVESTIGATION OF POLY(P-PHENYLENE) OBTAINED BY ELECTROCHEMICAL OXIDATION OF BENZENE IN A BUPYCL-ALCL3 MELT

被引：45

作者：

GOLDENBERG, LM

PELEKH, AE

KRINICHNYI, VI

ROSHCHUPKINA, OS

ZUEVA, AF

LYUBOVSKAYA, RN

EFIMOV, ON

机构：

[1] Institute of Chemical Physics, U.S.S.R. Academy of Sciences

来源：

SYNTHETIC METALS | 1990年 / 36卷 / 02期

关键词：

D O I：

10.1016/0379-6779(90)90054-O

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly(p-phenylene) has been obtained by electrochemical oxidation of benzene in a BuPyClAlCl3 melt. The conductivity of the fresh film is 10 - 100 S/cm. Even when the film is stored in a dry inert atmosphere, its conductivity is reduced. Electrochemical properties and IR and ESR spectra have been investigated. The polymer has an average chain length of 29 - 30 units. © 1990.

引用

页码：217 / 228

页数：12

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