THEORETICAL INTERPRETATION OF INFRARED-SPECTRA OF N-CYCLOHEXYL-2-PYRROLIDONE IN MIXTURES OF HEXANE AND CDCL3

被引：4

作者：

LOOS, D ^{[1
]}

PERJESSY, A ^{[1
]}

ENGBERTS, JBFN ^{[1
]}

机构：

[1] UNIV GRONINGEN,DEPT ORGAN & MOLEC INORGAN CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

MONATSHEFTE FUR CHEMIE | 1994年 / 125卷 / 03期

关键词：

N-CYCLOHEXYL-2-PYRROLIDONE; SOLVATION IN HEXANE-CDCL3 MIXTURE; AM1 INTERPRETATION OF INFRARED SPECTRA;

D O I：

10.1007/BF00811315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The infrared spectra of N-cyclohexyl-2-pyrrolidone (NCP) in binary mixtures of hexane and CDCl3 were interpreted theoretically in the region of C=O stretching vibrations using the AMI semiempirical method. The results were compared with those obtained for N,N-dimethylacetamide (DMA), cyclohexanone (CX) and propanone (PR). Good correlations were found between the carbonyl stretching frequencies and the theoretical parameters of free and solvated species in equilibria with hexane-CDCl3 solvent mixtures.

引用

页码：293 / 299

页数：7

共 8 条

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