SYNTHESIS AND MOLECULAR-STRUCTURE OF DISULFANE

被引：0

作者：

HAHN, J ^{[1
]}

SCHMIDT, P ^{[1
]}

REINARTZ, K ^{[1
]}

BEHREND, J ^{[1
]}

WINNEWISSER, G ^{[1
]}

YAMADA, KMT ^{[1
]}

机构：

[1] UNIV COLOGNE,INST ERSTES PHYS,W-5000 COLOGNE 41,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 10期

关键词：

DISULFANE; DEUTERODISULFANE; MOLECULAR STRUCTURE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structure of disulfane, H2S2, has been obtained by the cracking distillation of raw sulfane mixtures in a rotary evaporator, thus substituting the classical cracking column for the rotating flask of the evaporator. Pure, gaseous dideuterodisulfane could be generated by the solvolysis of bis(methyldiphenylsilyl)disulfane, (MePh2Si)2S2, with D2O in the presence of trichloroacetic acid as stabilizing agent. Partially deuterated disulfane has been prepared by H,D exchange between pure H2S2 and DCl. For the first time the molecular structure of HSSH has been determined based solely on microwave spectroscopy with the following parameters: r(SS) = 2.0564 angstrom, r(SH) = 1.342 angstrom, dihedral angle gamma = 90.34-degrees, and < (SSH) = 97.88-degrees.

引用

页码：1338 / 1342

页数：5

共 50 条

[21] FUNCTION AND PRESUMED MOLECULAR-STRUCTURE OF NA+-D-GLUCOSE COTRANSPORT SYSTEMS
KOEPSELL, H
SPANGENBERG, J
JOURNAL OF MEMBRANE BIOLOGY, 1994, 138 (01) : 1 - 11
[22] MOLECULAR-STRUCTURE OF POLYMERIZATION PRODUCT CONTAINING PHENYL-SILOXY AND DIPHENYLSILOXY UNITS
HAYASHIDA, S
IMAMURA, S
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (01) : 55 - 62
[23] STRATEGIES FOR DELIVERY OF PEPTIDE DRUGS TO THE CENTRAL-NERVOUS-SYSTEM - EXPLOITING MOLECULAR-STRUCTURE
BEGLEY, DJ
JOURNAL OF CONTROLLED RELEASE, 1994, 29 (03) : 293 - 306
[24] ISOLATION, PURIFICATION, AND MOLECULAR-STRUCTURE OF THE VASOACTIVE COMPONENT FROM RABBIT SKELETAL-MUSCLES
PETROVSKII, GG
TITOVETS, EP
BIOCHEMISTRY-MOSCOW, 1990, 55 (12) : 1591 - 1597
[25] THE CRYSTAL AND MOLECULAR-STRUCTURE OF N,N'-DIMETHYL-1,3-PROPANEDIAMMONIUM DITHIOCYANATE
CIUNIK, Z
DRABENT, K
POLISH JOURNAL OF CHEMISTRY, 1993, 67 (09) : 1631 - 1636
[26] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .29. SYNTHESIS AND MOLECULAR-STRUCTURE OF VINYLPYRIDINE DERIVATIVES OF RH6(CO)16
TUNIK, SP
POMOGAILO, SI
DZHARDIMALIEVA, GI
POMOGAILO, AD
CHUEV, II
ALDOSHIN, SM
NIKOLSKII, AB
RUSSIAN CHEMICAL BULLETIN, 1993, 42 (05) : 937 - 942
[27] The synthesis, molecular and electronic structure of cyanovinylidene complexes
Long, Ella M.
Brown, Neil J.
Man, Wing Y.
Fox, Mark A.
Yufit, Dmitry S.
Howard, Judith A. K.
Low, Paul J.
INORGANICA CHIMICA ACTA, 2012, 380 : 358 - 371
[28] Synthesis, molecular structure and reactivity of new biferrocenylpropane derivatives
Suo, Quan-Ling
Ma, Yan-Qiang
Wang, Yi-Bing
Han, Li-Min
Bai, Yue-Guang
Weng, Lin-Hong
JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (08) : 1234 - 1243
[29] Synthesis and crystal and molecular structure of a pulegone isoxazole derivative
Sadyrbekov, DT
Atazhanova, GA
Kulyyasov, AT
Raldugin, VA
Bagryanskaya, IY
Gatilov, YV
Edil'baeva, TT
Turdybekov, KM
Adekenov, SM
CHEMISTRY OF NATURAL COMPOUNDS, 2005, 41 (01) : 103 - 104
[30] Synthesis and Crystal and Molecular Structure of a Pulegone Isoxazole Derivative
D. T. Sadyrbekov
G. A. Atazhanova
A. T. Kulyyasov
V. A. Raldugin
I. Yu. Bagryanskaya
Yu. V. Gatilov
T. T. Edil’baeva
K. M. Turdybekov
S. M. Adekenov
Chemistry of Natural Compounds, 2005, 41 : 103 - 104

← 1 2 3 4 5 →