UNEXPECTED CROWN THIOETHER COMPLEXATION OF VANADIUM(IV) - ISOLATION AND STRUCTURAL CHARACTERIZATION OF [VOCL2([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE)

被引：33
|
作者：
WILLEY, GR
LAKIN, MT
ALCOCK, NW
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期
关键词：
D O I：
10.1039/c39910001414
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Contrary to hard and soft acid-base predictions the 'soft' crown thioether [9]aneS3 forms a stable 1:1 coordination complex with the extremely 'hard' vanadyl ion; [VOCl2([9]aneS3)] has a distorted octahedral structure with facial coordination (endodentate) of the trithiamacrocycle in a [2 + 1] bonding pattern, and provides the first example of a chelated high-valent group V-thioether complex.
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页码：1414 / 1416
页数：3
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