[LI(12-CROWN-4)]CL - CRYSTAL-STRUCTURE AND LR SPECTRUM

被引：35
作者：
GINGL, F
HILLER, W
STRAHLE, J
BORGHOLTE, H
DEHNICKE, K
机构：
[1] UNIV MARBURG,FACHBEREICH CHEM,HANS MEERWEIN STR,W-3550 MARBURG,GERMANY
[2] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN 1,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 606卷 / 15期
关键词：
LITHIUM CHLORIDE CROWN ETHER COMPLEX; IR SPECTRUM; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19916060109
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Colourless single crystals of [Li(12-crown-4)]Cl were obtained from acetonitrile solutions of LiCl in the presence of 12-crown-4. They were characterized by i. r. spectroscopy as well as by an X-ray structure determination. Space group P4/n, Z = 2, 1080 observed unique reflections, R = 0.034. Lattice dimensions at -50-degrees-C: a = 887.8(5), c = 752.0(2) pm. [Li(12-crown-4)]Cl forms ion paris with tetragonal symmetry and bond lengths Li-O of 212.8 pm and Li-Cl of 229.0 pm.
引用
收藏
页码：91 / 96
页数：6
相关论文
共 50 条
[31]   Preparation, Structural and Spectroscopic Characterization of a Pentaiodide [Rb(12-Crown-4)2]I5 [J].
Edis, Zehra ;
Bloukh, Samir Haj .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (12) :1340-1346
[32]   SYNTHESIS AND CRYSTAL-STRUCTURE OF [LI(DME)2I] [J].
RIFFEL, H ;
NEUMULLER, B ;
FLUCK, E .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (10) :1682-1684
[33]   Crystal structures of the alkali aluminoboracites A4B4Al3O12Cl (A = Li, Na) [J].
Yoshino, Sho ;
Arima, Hidechika ;
Ishijima, Masanao ;
Kajihara, Koichi .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 :169-+
[34]   COORDINATION-NUMBER 4 OR 6 FOR LITHIUM - THE CRYSTAL-STRUCTURE OF LITHIUM PERMANGANATE, LI[MNO4] [J].
FISCHER, D ;
HOPPE, R ;
SCHAFER, W ;
KNIGHT, KS .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (08) :1419-1425
[35]   PREPARATION AND CRYSTAL-STRUCTURE OF [P(C6H5)(4)]CL-3 [J].
JANSEN, M ;
STROJEK, S .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (08) :1171-1174
[36]   [Be(OH2)4]Cl2 -: Preparation, IR spectrum, and crystal structure [J].
Massa, Werner ;
Dehnicke, Kurt .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (09) :1366-1370
[37]   POLYSULFONYLAMINES .54. (12-CROWN-4)LITHIUM DIMESYLAMIDE-ACETONITRILE (3/2) - A CRYSTAL WITH 2 FUNDAMENTALLY DIFFERENT CONFORMATIONS OF THE SAME CORONAND [J].
BLASCHETTE, A ;
NAGEL, KH ;
JONES, PG .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (01) :36-42
[38]   CRYSTAL-STRUCTURE OF SBCL4F [J].
MINKWITZ, R ;
KONIKOWSKI, D ;
PREUT, H .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (01) :1-4
[39]   SYNTHESIS AND CRYSTAL-STRUCTURE OF LIHSO4 [J].
KEMNITZ, E ;
WERNER, C ;
WORZALA, H ;
TROJANOV, S ;
STRUTSCHKOV, YT .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (04) :675-678
[40]   THE CRYSTAL-STRUCTURE OF LITHIUMMETAPERIODATE, LIIO4 [J].
KRAFT, T ;
JANSEN, M .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (03) :484-487
12345