[LI(12-CROWN-4)]CL - CRYSTAL-STRUCTURE AND LR SPECTRUM

被引：35
|
作者：
GINGL, F
HILLER, W
STRAHLE, J
BORGHOLTE, H
DEHNICKE, K
机构：
[1] UNIV MARBURG,FACHBEREICH CHEM,HANS MEERWEIN STR,W-3550 MARBURG,GERMANY
[2] UNIV TUBINGEN,INST ANORGAN CHEM,W-7400 TUBINGEN 1,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 606卷 / 15期
关键词：
LITHIUM CHLORIDE CROWN ETHER COMPLEX; IR SPECTRUM; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19916060109
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Colourless single crystals of [Li(12-crown-4)]Cl were obtained from acetonitrile solutions of LiCl in the presence of 12-crown-4. They were characterized by i. r. spectroscopy as well as by an X-ray structure determination. Space group P4/n, Z = 2, 1080 observed unique reflections, R = 0.034. Lattice dimensions at -50-degrees-C: a = 887.8(5), c = 752.0(2) pm. [Li(12-crown-4)]Cl forms ion paris with tetragonal symmetry and bond lengths Li-O of 212.8 pm and Li-Cl of 229.0 pm.
引用
收藏
页码：91 / 96
页数：6
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