PHEROMONE SYNTHESIS .165. SYNTHESIS OF THE ENANTIOMERS OF RHYNCHOPHOROL [(E)-6-METHYL-2-HEPTEN-4-OL], THE MALE-PRODUCED AGGREGATION PHEROMONE OF THE AMERICAN PALM WEEVIL, RHYNCHOPHORUS-PALMARUM

被引：0

作者：

MORI, K

ISHIGAMI, K

机构：

来源：

LIEBIGS ANNALEN DER CHEMIE | 1992年 / 11期

关键词：

AMERICAN PALM WEEVIL; LIPASES; PHEROMONES; RHYNCHOPHOROL; RHYNCHOPHORUS-PALMARUM; ENZYMES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Both the enantiomers of rhynchophorol [(E)-6-methyl-2-hepten-4-ol (1)], the male-produced aggregation pheromone of the American palm weevil (Rhynchophorus palmarum), have bee synthesized by reducing their precursors, (R)- and (S)-6-methyl-2-heptyn-4-ol (2), which have been prepared by lipase-mediated asymmetric hydrolysis of the corresponding acetate and propionate.

引用

页码：1195 / 1198

页数：4

共 8 条

[1] ENANTIOSELECTIVE ESTERIFICATIONS OF UNSATURATED ALCOHOLS MEDIATED BY A LIPASE PREPARED FROM PSEUDOMONAS SP
BURGESS, K
JENNINGS, LD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) : 6129 - 6139
[2] SYNTHETIC STUDIES ON (2R,4'R,8'R)-ALPHA-TOCOPHEROL FACILE SYNTHESES OF OPTICALLY-ACTIVE, SATURATED, ACYCLIC ISOPRENOIDS VIA STEREOSPECIFIC [3,3] SIGMATROPIC REARRANGEMENTS
CHAN, KK
COHEN, N
DENOBLE, JP
SPECIAN, AC
SAUCY, G
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (22) : 3497 - 3505
[3] NUCLEAR MAGNETIC-RESONANCE ENANTIOMER REAGENTS - CONFIGURATIONAL CORRELATIONS VIA NUCLEAR MAGNETIC-RESONANCE CHEMICAL-SHIFTS OF DIASTEREOMERIC MANDELATE, O-METHYLMANDELATE, AND ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETATE (MTPA) ESTERS
DALE, JA
MOSHER, HS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) : 512 - 519
[4] MORI K, 1992, LIEBIGS ANN CHEM, P1191, DOI 10.1002/jlac.1992199201195
[5] PREPARATIVE BIO-ORGANIC CHEMISTRY .1. SYNTHESIS OF OPTICALLY-ACTIVE ALKYNYL ALCOHOLS AND ALPHA-HYDROXY ESTERS BY MICROBIAL ASYMMETRIC HYDROLYSIS OF THE CORRESPONDING ACETATES
MORI, K
AKAO, H
[J]. TETRAHEDRON, 1980, 36 (01) : 91 - 96
[6] OEHLSCHLAGER AC, 1992, NATURWISSENSCHAFTEN, V75, P134
[7] EVIDENCE FOR MALE-PRODUCED AGGREGATION PHEROMONE IN AMERICAN PALM WEEVIL, RHYNCHOPHORUS-PALMARUM (L) (COLEOPTERA, CURCULIONIDAE)
ROCHAT, D
GONZALEZ, A
MARIAU, D
VILLANUEVA, A
ZAGATTI, P
[J]. JOURNAL OF CHEMICAL ECOLOGY, 1991, 17 (06) : 1221 - 1230
[8] MALE-PRODUCED AGGREGATION PHEROMONE OF THE AMERICAN PALM WEEVIL, RHYNCHOPHORUS-PALMARUM (L) (COLEOPTERA, CURCULIONIDAE) - COLLECTION, IDENTIFICATION, ELECTROPHYSIOGICAL ACTIVITY, AND LABORATORY BIOASSAY
ROCHAT, D
MALOSSE, C
LETTERE, M
DUCROT, PH
ZAGATTI, P
RENOU, M
DESCOINS, C
[J]. JOURNAL OF CHEMICAL ECOLOGY, 1991, 17 (11) : 2127 - 2141

← 1 →