QUASI-ELASTIC LIGHT-SCATTERING FROM POLY(DIMETHYLSILOXANE) POLY(METHYL METHACRYLATE) CHLOROFORM UNDER THE OPTICAL THETA CONDITION

被引:13
|
作者
GIEBEL, L
BENMOUNA, M
BORSALI, R
FISCHER, EW
机构
[1] UNIV JOSEPH FOURIER,POB 53X,F-38041 GRENOBLE,FRANCE
[2] MAX PLANCK INST POLYMER RES,W-6500 MAINZ,GERMANY
[3] UNIV TLEMCEN,DEPT PHYS,TLEMCEN,ALGERIA
[4] CERMAV,CNRS,F-38041 GRENOBLE,FRANCE
关键词
D O I
10.1021/ma00062a007
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Quasielastic light scattering data are reported for a symmetrical mixture of PDMS/PMMA/chloroform satisfying the optical THETA condition. The measurements are made for several polymer concentrations ranging from approximately the overlap concentration to below the critical concentration for phase separation. The data are analyzed using a simple theory based on the random phase approximation. The Rouse model is sufficient to fit qualitatively the data, showing that hydrodynamic interaction is screened in the investigated range of concentration.
引用
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页码:2433 / 2438
页数:6
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