THE 2ND DIELECTRIC VIRIAL-COEFFICIENT OF ASYMMETRICAL POLAR HARD DUMBBELL FLUIDS

被引：1

作者：

OHBA, M ^{[1
]}

NOMURA, H ^{[1
]}

机构：

[1] NAGOYA UNIV,SCH ENGN,DEPT CHEM ENGN,CHIKUSA KU,NAGOYA,AICHI 464,JAPAN

来源：

MOLECULAR PHYSICS | 1990年 / 70卷 / 04期

关键词：

D O I：

10.1080/00268979000102691

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have calculated the second dielectric virial coefficient BΣ of some asymmetrical polar hard dumb-bell fluids. In the case of molecules with a short bond length, the effect of the asymmetry of molecular shapes is to increase BΣ. In contrast, for molecules with a long bond length, the effect is to decrease BΣ gradually. © 1990 Taylor & Francis Ltd.

引用

页码：729 / 733

页数：5

共 7 条

[1] THE STATISTICAL MECHANICS OF IMPERFECT POLAR GASES .2. DIELECTRIC POLARIZATION
BUCKINGHAM, AD
POPLE, JA
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1955, 51 (09): : 1179 - 1183
[2] THE DIELECTRIC CONSTANT OF AN IMPERFECT NON-POLAR GAS
BUCKINGHAM, AD
POPLE, JA
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1955, 51 (08): : 1029 - 1035
[3] 2ND VIRIAL-COEFFICIENTS FOR A FLUID OF DIPOLAR HARD ELLIPSOIDS
JOSLIN, CG
[J]. MOLECULAR PHYSICS, 1982, 47 (04) : 771 - 783
[4] CONTRIBUTION OF OFF-CENTRE DIPOLES TO SECOND VIRIAL COEFFICIENTS OF POLAR GASES
LAWLEY, KP
SMITH, EB
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1963, 59 (482): : 301 - &
[5] THE 2ND DIELECTRIC VIRIAL-COEFFICIENT OF NON-IDEAL POLAR HARD-SPHERE FLUIDS AND POLAR HARD DUMB-BELL FLUIDS
OHBA, M
NOMURA, H
[J]. MOLECULAR PHYSICS, 1988, 65 (06) : 1431 - 1439
[6] DIELECTRIC AND PRESSURE VIRIAL COEFFICIENTS OF IMPERFECT GASES .1. POLAR HALOGENATED METHANES
SUTTER, H
COLE, RH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (01) : 132 - &
[7] STATISTICAL MECHANICS OF LINEAR MOLECULES .4. NONSPHERICAL POLAR MOLECULES
SWEET, JR
STEELE, WA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1969, 50 (02) : 668 - &

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