INERTIAL DEFECTS OF PLANAR SYMMETRIC TOP MOLECULES

被引：26

作者：

JAGOD, MF ^{[1
]}

OKA, T ^{[1
]}

机构：

[1] UNIV CHICAGO,DEPT ASTRON & ASTROPHYS,CHICAGO,IL 60637

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1990年 / 139卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-2852(90)90068-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A general expression for the inertial defects of planar symmetric top molecules has been derived and applied to H3+, CH3+, C3H3+, and C6H6-type molecules. It has been found that the inertial derivatives anαα for these molecules can be expressed in terms of Coriolis constants. This allowed us to find a sufficient number of relations among Coriolis constants that the number of independent Coriolis constants is equal to the number of independent force constants. A numerical calculation of the inertial defect has been conducted for benzene, using Wilson's GF matrix method, and compared with experimental values. © 1990.

引用

页码：313 / 327

页数：15

共 44 条

[1]

Aliev M. R., 1985, MOL SPECTROSCOPY MOD, VIII, P1, DOI DOI 10.1016/B978-0-12-580643-5.50006-3

[2] DIFFERENCE FREQUENCY LASER SPECTROSCOPY OF THE UPSILON-3-BAND OF THE CH3 RADICAL [J].