Preparation of value-added metal-organic frameworks (MOFs) using waste PET bottles as source of acid linker

被引:55
作者
Dyosiba, Xoliswa [1 ,2 ]
Ren, Jianwei [1 ,2 ]
Musyoka, Nicholas M. [1 ]
Langmi, HenriettaW. [1 ]
Mathe, Mkhulu [1 ]
Onyango, Maurice S. [2 ]
机构
[1] CSIR, HySA Infrastruct Ctr Competence Mat Sci & Mfg, POB 395, ZA-0001 Pretoria, South Africa
[2] Tshwane Univ Technol, Dept Chem Met & Mat Engn, Private Bag X680, Pretoria, South Africa
基金
新加坡国家研究基金会;
关键词
Metal-organic framework; Waste PET; UiO-66(Zr); Hydrogen storage;
D O I
10.1016/j.susmat.2016.10.001
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Metal-organic frameworks (MOFs) have been considered with various novel applications and the development of cost-effective processes is essential for further practices. In this work, waste PET bottles were demonstrated as the source of acid linker to prepare value-added metal-organic frameworks UiO-66(Zr), and the texture properties as well as hydrogen storage capacity are comparable to those derived from commercial chemicals. This process offers an economically attractive strategy for eliminating waste PET stream while making value-added materials. (c) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:10 / 13
页数:4
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