NEW COORDINATION MODE OF 4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONATE(2-) IN POLYNUCLEAR GOLD(I) COMPLEXES - CRYSTAL-STRUCTURES OF [AU3(MU(3)-C3S5)(PPH3)3]CLO4 AND [AU4(MU-C3S5)2(MU-PH2PCH2PPH2)2]

被引：29

作者：

CERRADA, E

LAGUNA, A

LAGUNA, M

JONES, PG

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 08期

关键词：

D O I：

10.1039/dt9940001325

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligand 4,5-dimercapto-1,3-dithiole-2-thionate(2-) (C3S52-) has been transferred from [NEt4]2-[Zn(C3S5)2] to gold(I) centres. affording di-, tri- or tetra-nuclear complexes containing the C3S52- ligand in unprecedented mu- or mu3-bridging forms.

引用

页码：1325 / 1326

页数：2

共 17 条

[1] SYNTHESIS AND STRUCTURE OF 1,3-DIPHENYLTRIAZENIDOGOLD(I), A TETRAMERIC MOLECULE WITH SHORT GOLD GOLD DISTANCES [J].

BECK, J ;

STRAHLE, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (01) :95-96

[2] HIGHLY CONDUCTING CHARGE-TRANSFER COMPOUNDS OF TETRATHIAFULVALENE AND TRANSITION-METAL DMIT COMPLEXES [J].

BOUSSEAU, M ;

VALADE, L ;

LEGROS, JP ;

CASSOUX, P ;

GARBAUSKAS, M ;

INTERRANTE, LV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) :1908-1916

[3] CONDUCTIVE MOLECULAR-CRYSTALS FROM 3-DIMENSIONAL BUILDING-BLOCKS - SYNTHESIS AND CHARACTERIZATION OF TRIS(BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM) BIS(TRIS(2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATO)VANADATE), [ET]3[V(DMIT)3]2, AND THE CORRESPONDING TETRAMETHYLTETRASELENFULVALENIUM SALT [J].

BRODERICK, WE ;

MCGHEE, EM ;

GODFREY, MR ;

HOFFMAN, BM ;

IBERS, JA .

INORGANIC CHEMISTRY, 1989, 28 (15) :2902-2904

[4]

BROSSARD L, 1988, SYNTHETIC MET, V27, pB157, DOI 10.1016/0379-6779(88)90139-7

[5] MOLECULAR-METALS AND SUPERCONDUCTORS DERIVED FROM METAL-COMPLEXES OF 1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE (DMIT) [J].

CASSOUX, P ;

VALADE, L ;

KOBAYASHI, H ;

KOBAYASHI, A ;

CLARK, RA ;

UNDERHILL, AE .

COORDINATION CHEMISTRY REVIEWS, 1991, 110 (01) :115-160

[6] GOLD DITHIOCARBOXYLATES [J].

CHIARI, B ;

PIOVESANA, O ;

TARANTELLI, T ;

ZANAZZI, PF .

INORGANIC CHEMISTRY, 1985, 24 (03) :366-371

[7] SYNTHESES AND CHARACTERIZATION OF DINUCLEAR GOLD(I) RING AND OPEN-RING COMPLEXES CONTAINING SATURATED AND UNSATURATED DITHIOL BRIDGING LIGANDS AND PHOSPHINE OR BIS(DIPHOSPHINE) DONOR LIGANDS - CRYSTAL-STRUCTURES OF [AU2(MU-S(CH2)3S)(MU-DPPM)],[AU2(MU-MNT)(PPH3)2], [AU2(MU-S2C6H4)(PPH3)2], AND [AU4(MU-S2C6H3CH3)2(PET3)2] [J].

DAVILA, RM ;

ELDUQUE, A ;

GRANT, T ;

STAPLES, RJ ;

FACKLER, JP .

INORGANIC CHEMISTRY, 1993, 32 (09) :1749-1755

[8] THE 1ST MOLECULAR SUPERCONDUCTOR BASED ON PI-ACCEPTOR MOLECULES AND CLOSED-SHELL CATIONS, [(CH3)4N][NI(DMIT)2]2, LOW-TEMPERATURE X-RAY STUDIES AND SUPERCONDUCTING TRANSITION [J].

KOBAYASHI, A ;

KIM, H ;

SASAKI, Y ;

KATO, R ;

KOBAYASHI, H ;

MORIYAMA, S ;

NISHIO, Y ;

KAJITA, K ;

SASAKI, W .

CHEMISTRY LETTERS, 1987, (09) :1819-1822

[9] MOLECULAR-INTERACTIONS, BAND-STRUCTURE, AND BEDT-TTF OXIDATION-STATES IN THE MOLECULAR CONDUCTOR (BEDT-TTF)3[V(DMIT)3]2 [J].

MARTIN, JD ;

CANADELL, E ;

BATAIL, P .

INORGANIC CHEMISTRY, 1992, 31 (14) :3176-3178

[10] SPECTROSCOPIC AND ELECTRICAL-PROPERTIES OF VO (2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATE)2 AND V (2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATE)3 ANION COMPLEXES AND X-RAY CRYSTAL-STRUCTURE OF [N-METHYLPHENAZINIUM]2[V(2-THIOXO-1,3-DITHIOLE-4,5-DITHOLATE(3] [J].

MATSUBAYASHI, G ;

AKIBA, K ;

TANAKA, T .

INORGANIC CHEMISTRY, 1988, 27 (26) :4744-4749

← 1 2 →