CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(ETA(5)-METHYLCYCLOPENTADIENYL)TITANA(IV)-CYCLOHEXASULFANE, TI(ETA(5)-C5H4CH3)(2)S-5

被引：6

作者：

KLOURAS, N ^{[1
]}

DEMAKOPOULOS, I ^{[1
]}

TERZIS, A ^{[1
]}

RAPTOPOULOU, CP ^{[1
]}

机构：

[1] NCSR DEMOKRITOS,INST MAT SCI,GR-15310 ATHENS,GREECE

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 01期

关键词：

METALLACYCLOHEXASULFANES; TITANOCENE PENTASULFIDE CHELATES; X-RAY ANALYSIS;

D O I：

10.1002/zaac.19956210121

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of Ti(eta(5)-C5H4CH3)(2)S-5 has been determined by X-ray diffraction studies. The substance crystallizes in the monoclinic crystal system [a = 6.8642(5), b = 16.507(1), c = 13.074(1) Angstrom, beta = 82.407(3)degrees, space group P2(1)/n, Z = 4]. The geometry about the titanium atom is a distorted tetrahedron, with a (centroid)Ti-(centroid) angle of 131.29 degrees and a S-Ti-S angle of 93.38 degrees. The six-membered ring TiS5 has a cyclohexane-like chair configuration. The structural results are compared to those for similar type titanium complexes.

引用

页码：113 / 116

页数：4

共 9 条

[1] CRYSTAL AND MOLECULAR STRUCTURE OF S6 (SULFUR-6) [J].