POLYPROPYLENE SEPARATOR GRAFTED WITH HYDROPHILIC MONOMERS FOR LITHIUM BATTERIES

被引：44

作者：

GINESTE, JL ^{[1
]}

POURCELLY, G ^{[1
]}

机构：

[1] CNRS,MAT & PROCEDES MEMBRANES LAB,UMR 9987,F-34033 MONTPELLIER,FRANCE

来源：

JOURNAL OF MEMBRANE SCIENCE | 1995年 / 107卷 / 1-2期

关键词：

GRAFTED SEPARATOR; KINETICS OF GRAFTING; HYDROPHILIC MONOMER; LITHIUM BATTERY; CYCLING PERFORMANCES;

D O I：

10.1016/0376-7388(95)00112-P

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Separator materials play an important part in lithium nonaqueous rechargeable battery operation. Their wettability limits the performances of batteries. To avoid wetting agents or undesirable substances to the electrode system, grafted separators are used. Acrylic acid (AA) and diethyleneglycol-dimethacrylate (DEGDM) are grafted onto 50 mu m polypropylene films. The physicochemical properties of the polymer films obtained are studied versus the characteristics of grafting. The influence of temperature and monomer content on grafting kinetics is pointed out. Cycling performances of secondary lithium batteries including these grafted films as separators are also presented.

引用

页码：155 / 164

页数：10

共 19 条

[1] DIRECTIONS IN SECONDARY LITHIUM BATTERY RESEARCH-AND-DEVELOPMENT [J].

ABRAHAM, KM .

ELECTROCHIMICA ACTA, 1993, 38 (09) :1233-1248

[2]

BLOMGREN GE, 1983, LITHIUM BATTERIES, pCH2

[3]

CHAPIRO A, 1988, J POLYM SCI, V29, P321

[4] GRAFTING OF ACRYLIC-ACID WITH DIETHYLENEGLYCOL DIMETHACRYLATE ONTO RADIOPEROXIDED POLYETHYLENE [J].

GINESTE, JL ;

GARAUD, JL ;

POURCELLY, G .

JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 48 (12) :2113-2122

[5] SYNTHESIS AND CHARACTERIZATION OF POLYETHYLENE FILM GRAFTED WITH ACRYLIC-ACID AND DIETHYLENEGLYCOL-DIMETHACRYLATE [J].

GINESTE, JL ;

GARAUD, JL ;

POURCELLY, G .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (12) :2969-2975

[6] KINETIC-STUDY OF ACRYLIC MONOMER GRAFTING IN THE PRESENCE OF A POLYFUNCTIONAL MONOMER ONTO RADIOPEROXIDED POLY(ETHYLENE TETRAFLUOROETHYLENE) COPOLYMER [J].

GINESTE, JL ;

LARGUEZE, C ;

POURCELLY, G .

JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 51 (01) :63-70

[7]

GINESTE JL, 1993, Patent No. 93402037

[8]

Helfferich F., 1962, ION EXCHANGE

[9]

HOFFMAN DK, 1991, 5TH P INT SEM LITH B

[10]

LABAT J, 1990, EXTRAITS REV GENERAL

← 1 2 →