SYNTHESIS, STRUCTURES, AND REACTIONS OF ETHENETHIOLATO COMPLEXES OF MOLYBDENUM AND TUNGSTEN [M(ETA-3-SC(CF3)=C(CF3)H)(CF3C=CCF3)(ETA-5-C5H5)](M = MO OR W) - THEIR RELEVANCE TO THE MECHANISM OF METAL-PROMOTED ISOMERIZATION OF CARBON - CARBON DOUBLE-BONDS

被引：5
作者：
AGHATABAY, NM [1 ]
DAVIDSON, JL [1 ]
机构：
[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1989年 / 06期
关键词：
D O I：
10.1039/dt9890001027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
引用
收藏
页码：1027 / 1035
页数：9
相关论文
共 48 条
[1]   METAL-PROMOTED INSERTION AND CYCLIZATION REACTIONS OF ALKYNES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [MO(ETA-4-C(CF3)=C(CF3)C(CF3)=C(CF3)SPRI)(PET3)(ETA-5-C5H5)] AND [MO(ETA-1-C(CF3)=C(CF3)SC6F5)(CF3C=CCF3)(O)(ETA-5-C5H5)] [J].
ABUBAKAR, WAW ;
CARLTON, L ;
DAVIDSON, JL ;
MANOJLOVICMUIR, L ;
MUIR, KW .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 352 (03) :C54-C58
[2]   THE MECHANISM OF ISOMERIZATION OF THE C=C BOND IN ETHENETHIOLATO LIGANDS COORDINATED TO MOLYBDENUM AND TUNGSTEN - THE MOLECULAR-STRUCTURES OF (E)-EXO-(W)ETA-3-SC(CF3)=C(CF3)H)(CF3C=CCF3)(ETA-5-C5H5)] AND (Z)-ENDO-[W)ETA-3-SC(CF3)=C(CF3)H)(CF3C=CCF3)(ETA-5-C5H5)] [J].
AGHATABAY, NM ;
DAVIDSON, JL ;
DOUGLAS, G ;
MUIR, KW .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (20) :1526-1528
[3]   REACTIONS OF COORDINATED LIGANDS .24. THE REACTION OF BIS(BUT-2-YNE)CARBONYL(ETA-CYCLOPENTADIENYL OR ETA-5-INDENYL)MOLYBDENUM TETRAFLUOROBORATE WITH ACETONITRILE AND PHOSPHINES - CRYSTAL-STRUCTURES OF BUT-2-YNECARBONYL(ETA-5-INDENYL)(TRIETHYLPHOSPHINE)MOLYBDENUM TETRAFLUOROBORATE AND BUT-2-YNE(ETA-5-INDENYL)BIS(TRIMETHYLPHOSPHINE)MOLYBDENUM TETRAFLUOROBORATERU [J].
ALLEN, SR ;
BAKER, PK ;
BARNES, SG ;
GREEN, M ;
TROLLOPE, L ;
MANOJLOVICMUIR, L ;
MUIR, KW .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (03) :873-883
[4]   REACTIONS OF COORDINATED LIGANDS .29. THE FORMATION OF A 1,3-DIENE AT A MOLYBDENUM CENTER BY LINKING OF BUT-2-YNE WITH AN ALKENE - X-RAY CRYSTAL-STRUCTURES OF [MO(ETA-2-ORTHO-PH2PC6H4CH=CH2)(ETA-2-MEC2ME)(ETA-C5H5)]-[BF4] AND [MO(NCME)(ETA-4-ORTHO-MECH=CME-CH=CHC6H4PPH2)(ETA-C5H5)]-[BF4] [J].
ALLEN, SR ;
GREEN, M ;
MORAN, G ;
ORPEN, AG ;
TAYLOR, GE .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (03) :441-449
[5]  
BOWER DC, 1986, ORGANOMETALLICS, V5, P95
[6]   THE REACTIONS OF SIGMA,ETA-3-BUTADIENYLRUTHENIUM COMPLEXES WITH DONOR LIGANDS AND PROTONS - STRUCTURES OF [RUC(PH)=C(PH)-ETA-2-((Z)-C(PH)=CH(PH))(P(OME)3)(ETA-C5H5)] AND [RUC(O)C(PH)=C(PH)-ETA-2-((Z)-C(PH)=CH(PH))(P(OME)3)(ETA-C5H5)] [J].
BRAMMER, L ;
CROCKER, M ;
DUNNE, BJ ;
GREEN, M ;
MORTON, CE ;
NAGLE, KR ;
ORPEN, AG .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (15) :1226-1228
[7]   CARBON-HYDROGEN-TRANSITION METAL BONDS [J].
BROOKHART, M ;
GREEN, MLH .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :395-408
[8]   TUNGSTEN AND MOLYBDENUM 2-OXAALLYL (ETA-1-(C)-ENOLATE) COMPLEXES - FUNCTIONAL-GROUP TRANSFORMATIONS, PHOTOCHEMICAL ALDOL REACTIONS, AND ALKYNE/CO MIGRATORY INSERTION REACTIONS [J].
BURKHARDT, ER ;
DONEY, JJ ;
BERGMAN, RG ;
HEATHCOCK, CH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (07) :2022-2039
[9]   SYNTHESIS, REACTIONS, AND DYNAMIC NUCLEAR-MAGNETIC-RESONANCE STUDIES OF ETA-2-VINYL COMPLEXES OF TUNGSTEN, [W(ETA-3-C(CF3)C(CF3)(SR))(CF3C=CCF3)(ETA-5-C5H5)] (R = ME, ET, PRN, PRI, OR BUT) [J].
CARLTON, L ;
DAVIDSON, JL .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (04) :895-905
[10]   THE MECHANISTIC ROLE OF ETA-2-VINYL COMPLEXES IN METAL-PROMOTED ALKYNE OLIGOMERIZATIONS - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [W(ETA-5-C(CF3)=C(CF3)C(CO2ME)=C(CO2ME)C(CF3)=C(CF3)SPRI)(ETA-5-C5H5)], [WF(ETA-5-C(=CF2)C(CF3)=C(CO2ME)C(CO2ME)C(CF3)C(CF3)SPRI)(ETA-5-C5H5)], AND [W(ETA-4-C(CF3)C(CF3)=C(ME)C(ME)SPRI)(ETA-2-CF3C=CCF3)(ETA-5-C5H5)]) [J].
CARLTON, L ;
DAVIDSON, JL ;
EWING, P ;
MANOJLOVICMUIR, L ;
MUIR, KW .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (21) :1474-1476
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