SYNTHESIS OF A NOVEL DONOR, BTFE-DMB, AND THE ELECTRICAL-PROPERTIES OF ITS IODINE SALTS

被引：19

作者：

MIZUTANI, M

TANAKA, K

IKEDA, K

KAWABATA, K

机构：

[1] Central Research Laboratories, Idemitsu Kosan Co., Ltd., Sodegaura, Chiba, 299-02

来源：

SYNTHETIC METALS | 1992年 / 46卷 / 02期

关键词：

D O I：

10.1016/0379-6779(92)90343-H

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

1,4-Bis[2(tetrathiafulvalen-2-yl)ethenyl]-2,5-dimethylbenzene (BTFE-DMB) is synthesized. Both the absolute values of oxidation potentials and the difference between the first and second ones of BTFE-DMB are smaller than those of tetrathiafulvalene (TTF). The resistivity of the single crystal of its iodine salts is as low as 7 x 10(-3)-OMEGA-cm at room temperature. The crystal shows a metallic-conducting behavior above c. 180 K.

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页码：201 / 205

页数：5

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