ACID MEDIATED INTRAMOLECULAR CYCLIZATION OF PI-DONORS BEARING 2 VICINAL CIS-BRANCHED, 1,4-DITHIAFULVEN-6-YL SUBSTITUENTS ON A C=C BOND

被引：22
作者：
BENAHMEDGASMI, AS
FRERE, P
BELYASMINE, A
MALIK, KMA
HURSTHOUSE, MB
MOORE, AJ
BRYCE, MR
JUBAULT, M
GORGUES, A
机构：
[1] UNIV ANGERS,CHIM ORGAN FONDAMENTALE & APPLIQUEE LAB,2 BD LAVOISIER,F-49045 ANGERS,FRANCE
[2] UNIV ORAN,CHIM ORGAN LAB,ORAN,ALGERIA
[3] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES
[4] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 13期
关键词：
PI-DONORS; TETRATHIAFULVALENE (TTF) ANALOGS; ORGANIC CONDUCTORS; WITTIG(-HORNER) REACTIONS; INTRAMOLECULAR CYCLIZATIONS;
D O I：
10.1016/S0040-4039(00)60363-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cis-ethylenic analogues 1 and ortho-benzenic analogues 2 of TTF undergo a rapid acid mediated intramolecular cyclization into the corresponding cycloisomers 1' and 2' whose structures are confirmed by X-ray diffraction; as shown by cyclic voltammetry, compounds 1 may act as convenient precursors of organic metals.
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收藏
页码：2131 / 2134
页数：4
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