PI/SIGMA EQUILIBRIA IN RHENIUM KETONE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(O=CRR')]+X- - A MARKED ELECTRONIC EFFECT UPON THE BINDING MODE

被引：35

作者：

KLEIN, DP

DALTON, DM

MENDEZ, NQ

ARIF, AM

GLADYSZ, JA

机构：

[1] Department of Chemistry, University of Utah, Salt Lake City

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 412卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)86066-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first series of metal ketone complexes for which both sigma and pi isomers can be isolated is reported. Electron-withdrawing substituents favor the pi binding mode.

引用

页码：C7 / C10

页数：4

共 13 条

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