MISCIBILITY OF POLY(VINYL ALCOHOL) POLY(METHACRYLIC ACID) AND POLY(VINYL ALCOHOL) POLY(ACRYLIC ACID) SYSTEMS .1. HIGH-RESOLUTION NMR-STUDIES IN SOLUTION

被引：30
|
作者：
ZHANG, XQ [1 ]
TAKEGOSHI, K [1 ]
HIKICHI, K [1 ]
机构：
[1] HOKKAIDO UNIV,FAC SCI,DEPT POLYMER SCI,SAPPORO,HOKKAIDO 060,JAPAN
来源：
POLYMER JOURNAL | 1991年 / 23卷 / 02期
关键词：
POLY(VINYL ALCOHOL); POLY(METHACRYLIC ACID); POLY(ACRYLIC ACID); HIGH-RESOLUTION NMR; NUCLEAR OVERHAUSER EFFECT; POLYMER BLENDS; POLYMER COMPLEXES; MISCIBILITY; HYDROGEN-BONDING INTERACTION; PROTON CHEMICAL EXCHANGE;
D O I：
10.1295/polymj.23.79
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Miscibility in two-component polymer systems of poly(vinyl) alcohol)/poly(methacrylic acid) (PVA/PMAA) and poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) in dimethylsulfoxide (DMSO) solution was examined by high-resolution NMR. Intermolecular NOE was observed between PVA and PMAA or PAA. The results indicate that the PVA and PMAA or PAA are intimately mixed on a scale less than 4-angstrom. The chemical shifts of COOH resonances of PMAA and PAA and the OH resonance of PVA suggest the existence of hydrogen-bonding interaction between the two different polymers.
引用
收藏
页码：79 / 86
页数：8
相关论文
共 50 条
  • [1] MISCIBILITY OF POLY(VINYL ALCOHOL) POLY(METHACRYLIC ACID) AND POLY(VINYL ALCOHOL POLY(ACRYLIC ACID) SYSTEMS .2. HIGH-RESOLUTION SOLID-STATE CP MAS C-13 NMR-STUDIES
    ZHANG, XQ
    TAKEGOSHI, K
    HIKICHI, K
    POLYMER JOURNAL, 1991, 23 (02) : 87 - 93
  • [2] PHASE-SEPARATION AND THERMAL-DEGRADATION OF POLY(VINYL ALCOHOL) POLY(METHACRYLIC ACID) AND POLY(VINYL ALCOHOL) POLY(ACRYLIC ACID) SYSTEMS BY C-13 CP/MAS NMR
    ZHANG, XQ
    TAKEGOSHI, K
    HIKICHI, K
    POLYMER, 1992, 33 (04) : 718 - 724
  • [3] Grafting of poly(methacrylic acid) on starch and poly(vinyl alcohol)
    Beliakova, MK
    Aly, AA
    Abdel-Mohdy, FA
    STARCH-STARKE, 2004, 56 (09): : 407 - 412
  • [4] INTERMOLECULAR INTERACTIONS IN BLENDS OF POLY(VINYL ALCOHOL) WITH POLY(ACRYLIC ACID) .1. FTIR AND DSC STUDIES
    DANILIUC, L
    DEKESEL, C
    DAVID, C
    EUROPEAN POLYMER JOURNAL, 1992, 28 (11) : 1365 - 1371
  • [5] Intermolecular interactions in blends of poly(vinyl alcohol) with poly(acrylic acid) - 1. FTIR and DSC studies
    Daniliuc, L., 1600, (28):
  • [6] Highly lubricious poly(vinyl alcohol)-poly(acrylic acid) hydrogels
    Choi, Jeeyoung
    Kung, Hsiang J.
    Macias, Celia E.
    Muratoglu, Orhun K.
    JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2012, 100B (02) : 524 - 532
  • [7] The actuation of a biomimetic poly(vinyl alcohol)-poly(acrylic acid) gel
    Marra, SP
    Ramesh, KT
    Douglas, AS
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2002, 360 (1791): : 175 - 198
  • [8] Poly(acrylic acid) poly(vinyl alcohol) copolymers with superabsorbent properties
    Argade, AB
    Peppas, NA
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 70 (04) : 817 - 829
  • [9] Viscosimetric study of poly(vinyl alcohol) poly(styrenesulfonic acid) miscibility in dilute aqueous solution
    MBareck, CO
    Metayer, M
    Langevin, D
    Roudesli, S
    JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 62 (01) : 161 - 165
  • [10] POLY(VINYL ALCOHOL) POLY(ACRYLIC ACID) BLENDS - MISCIBILITY STUDIES BY DSC AND CHARACTERIZATION OF THEIR THERMALLY-INDUCED HYDROGELS
    VAZQUEZTORRES, H
    CAUICHRODRIGUEZ, JV
    CRUZRAMOS, CA
    JOURNAL OF APPLIED POLYMER SCIENCE, 1993, 50 (05) : 777 - 792
12345