AROMATIZATION OF 1,3-BUTADIENE UNDER PRESSURE

被引：2
|
作者：
CYPRES, R [1 ]
BRAEKMANDANHEUX, C [1 ]
DELAUNOIS, C [1 ]
HALLOIN, V [1 ]
机构：
[1] UNIV LIBRE BRUXELLES,FAC SCI APPL,SERV CHIM GEN & CARBOCHIM,50 AVE FD ROOSEVELT,B-1050 BRUSSELS,BELGIUM
来源：
THERMOCHIMICA ACTA | 1991年 / 179卷
关键词：
D O I：
10.1016/0040-6031(91)80338-J
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The aromatisation of 1,3-butadiene has been performed under pressure in inert and reactive atmospheres. The influence of industrial catalysts has also been studied. The results, as expected, show that pressure plays an important role in the Diels-Alder reaction of the dimerisation of 1,3-butadiene to 4-vinylcyclohexene. The catalysts used are not efficient in view of the high yield of light aromatic hydrocarbons. A three-step procedure is proposed to optimise the aromatisation of short chain olefins.
引用
收藏
页码：99 / 107
页数：9
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