New Correlations for Coal and Biomass Pyrolysis Performances with Coal-Biomass Type Number and Temperature

被引:11
作者
Bindar, Yazid [1 ]
机构
[1] Inst Teknol Bandung, Res Grp Energy & Proc Syst Chem Engn, Dept Chem Engn, Fac Ind Technol, Jalan Ganesa 10, Bandung 40132, Indonesia
来源
JOURNAL OF ENGINEERING AND TECHNOLOGICAL SCIENCES | 2013年 / 45卷 / 03期
关键词
Coal-biomass type number; emperical pyrolysis correlations; pyrolysis performance; volatile components; volatile proximate matter; volatile yield;
D O I
10.5614/j.eng.technol.sci.2013.45.3.5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The pyrolysis of coal and biomass is generally reported as the mass yield of released chemicals at various temperatures, pressures, heating rates and coal or biomass type. In this work, a new coal-biomass type number, NCT, is introduced. This number is constructed from the mass fractions of carbon, hydrogen, and oxygen in the ultimate analysis. This number is unique for each coal or biomass type. For 179 different species of coal and biomass from the literature, the volatile matter mass yield can be expressed by the second order polynomial function ln(NCT). This unique correlation allows the effects of the temperature and heating rate on the volatile yield YVY for coal and biomass to be empirically correlated as well. The correlation for the mass fraction of each chemical component in the released volatile matter correlation is obtained from the YVY correlation. The weight factor for some of the components is constant for the variation of NCT, but not for others. The resulted volatile matter and yield correlations are limited to atmospheric pressure, very small particles (less than 0.212 mm) and interpreted for wire-mesh pyrolysis reactor conditions and a nitrogen gas environment.
引用
收藏
页码:275 / 293
页数:19
相关论文
共 25 条
[1]  
Niksaa S., Liua G.S., Hurtb R.H., Coal Conversion Submodels for Design Applications at Elevated Pressures. Part I. Devolatilization and Char Oxidation, Progress in Energy and Combustion Science, 29, pp. 425-477, (2003)
[2]  
Mill C.J., Pyrolysis of Fine Coal Particles at High Heating Rate and Pressure, (2000)
[3]  
Genetti D.B., An Advanced Model of Coal Devolatilization Based on Chemical Structure, (1999)
[4]  
Schlosberg R.H., Chemistry of Coal Conversion, (1985)
[5]  
Solomon P.R., Hamblen D.G., Carangelo R.M., Serio M.A., Deshpande G.V., General Model for Coal Devolatilazation, Energy and Fuels, 2, pp. 405-422, (1988)
[6]  
Xu W., Tomita A., Effect of Coal Type on the Flash Pyrolysis of Various Coals, Fuel, 66, pp. 627-631, (1987)
[7]  
Lee C.W., Scaroni A.W., Jenkins R.G., Effect of Pressure on the Devolatilization and Swelling Behaviour of a Softening Coal during Rapid Heating, Fuel, 70, pp. 957-965, (1991)
[8]  
Fatemi M., Effect of Pressure on Pyrolysis of a Sub-Bituminous Coal in an Entrained-Flow Reactor, Am. Chem. Soc. Div. Fuel Chem, 32, pp. 117-124, (1987)
[9]  
Yeasmin H., Mathews J.F., Ouyang S., Rapid Pyrolysis of Yallourn Brown Coal at High Pressures and Temperatures, Fuel, 78, pp. 11-24, (1999)
[10]  
Zeng D., Effect of Pressure on Coal Pyrolysis at High Heating Rates and, (2005)