NOVEL CHLOROTRIMETHYLSILANE CATALYZED STEREOSELECTIVE DECONJUGATION OF BETA-BROMO (OR IODO) SUBSTITUTED ALPHA,BETA-UNSATURATED ACYCLIC KETONE

被引：13

作者：

LUO, FT

HSIEH, LC

机构：

[1] Institute of Chemistry, Academia Sinica, Nankang, Taipei

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 51期

关键词：

D O I：

10.1016/0040-4039(94)88517-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

TMSCl catalyzed stereoselective isomerization (deconjugation) of beta-substituted alpha,beta-unsaturated ketones to the corresponding (Z)-beta,gamma-unsaturated ketones and its mechanism studies are described.

引用

页码：9585 / 9588

页数：4

共 5 条

[1] PHOTOCHEMICAL DECONJUGATION OF ALPHA,BETA-UNSATURATED KETONES [J].

ENG, SL ;

RICARD, R ;

WAN, CSK ;

WEEDON, AC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (05) :236-238

[2]

HERMANN JL, 1973, TETRAHEDRON LETT, P2433

[3]

KANEKO C, 1973, TETRAHEDRON LETT, P2339

[4] A NOVEL STEREOSELECTIVE SYNTHESIS OF (Z)-3-IODO-3-ALKEN-1-ONE FROM 2-ALKYN-1-ONE [J].

LUO, FT ;

KUMAR, KA ;

HSIEH, LC ;

WANG, RT .

TETRAHEDRON LETTERS, 1994, 35 (16) :2553-2554

[5]

RATHKE MW, 1972, TETRAHEDRON LETT, P4249

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