KINETICS AND MECHANISM OF THE THERMAL-DECOMPOSITION OF LANTHANUM COMPLEXES OF 4-N-(4'-ANTIPYRYLMETHYLIDENE) AMINOANTIPYRINE

被引：23

作者：

NAIR, MKM ^{[1
]}

RADHAKRISHNAN, PK ^{[1
]}

机构：

[1] MAHATMA GANDHI UNIV,SCH CHEM SCI,KOTTAYAM 686560,KERALA,INDIA

来源：

THERMOCHIMICA ACTA | 1995年 / 261卷

关键词：

COATS-REDFERN; DECOMPOSITION; KINETICS; LANTHANUM COMPLEXES;

D O I：

10.1016/0040-6031(95)02313-Q

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The kinetics and mechanism of the thermal decomposition of perchlorate, nitrate, chloride, bromide, and iodide complexes of lanthanum with the Schiff base 4-N-(4'-antipyrylmethylidene) aminoantipyrine(abbreviated as AA) have been studied by TG and DTG techniques. The kinetic parameters for the major decomposition stages (stages I and II) were calculated using the Coats-Redfern equation. The rate-controlling process obeys Mampel's model with random nucleation, with one nucleus on each particle. It is observed that there is no regular variation in the values of the kinetic parameters of decomposition of the complexes as with other common physical constants, namely boiling point, melting point, etc.

引用

页码：141 / 149

页数：9

共 20 条

[1] THERMAL-DECOMPOSITION KINETICS OF 2-FURALDEHYDE THIOSEMICARBAZONE COMPLEXES OF CADMIUM(II) AND MERCURY(II) [J].

ARAVINDAKSHAN, KK ;

MURALEEDHARAN, K .

THERMOCHIMICA ACTA, 1989, 155 :247-253

[2]

BHASKARE CK, 1981, P NATIONAL S THERMAL

[3]

COATS AW, 1964, NATURE, V210, P68

[4]

DEAN J, 1976, LANGES HDB CHEM

[5] THERMAL-DECOMPOSITION KINETICS OF ZIRCONYL OXALATE, ZIRCONYL OXALIC-ACID AND AMMONIUM ZIRCONYL OXALATE [J].

DEVI, TG ;

MURALEEDHARAN, K ;

KANNAN, MP .

THERMOCHIMICA ACTA, 1991, 191 (01) :105-113

[6]

HILL JO, 1975, THERMOCHIM ACTA, V11, P301

[7]

HILL JO, 1976, J THERM ANAL, V9, P415

[8] THERMOGRAVIMETRY OF SOME NOBLE AND COMMON METAL-CHELATES OF 1,3,4-THIADIAZOLE-2-THIOL-5-AMINO AND N-ACETYLACETONE-ANTHRANILIC ACID [J].

JOHRI, KN ;

ARORA, BS .

THERMOCHIMICA ACTA, 1982, 54 (1-2) :237-241

[9]

LEHTINEN M, 1981, ACTA PHARM FENN, V90, P187

[10] THERMAL-DECOMPOSITION KINETICS .15. KINETICS AND MECHANISM OF THERMAL-DECOMPOSITION OF TETRAMMINE COPPER(II) SULFATE MONOHYDRATE [J].

MATHEW, S ;

NAIR, CGR ;

NINAN, KN .

THERMOCHIMICA ACTA, 1989, 144 (01) :33-43

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