STRUCTURAL-ANALYSIS OF SUCCINOYLATED AND CHLOROFORMATE ACTIVATED PULLULAN - NMR-STUDY IN DMSO SOLUTION

被引：20

作者：

BRUNEEL, D ^{[1
]}

SCHACHT, E ^{[1
]}

DEBRUYN, A ^{[1
]}

机构：

[1] STATE UNIV GHENT,ORGAN CHEM LAB,KRIJGSLAAN 281 S4,B-9000 GHENT,BELGIUM

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1993年 / 12卷 / 06期

关键词：

D O I：

10.1080/07328309308019006

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A new technique is proposed in order to assign the substitution sites of pullulan after a reaction. The OH proton resonances of pullulan are identified in DMSO solution, after complete analysis of its proton spectrum using Correlated Spectroscopy (COSY) and Homonuclear Hartmann-Hahn (HOHAHA) experiments.

引用

页码：769 / 778

页数：10

共 13 条

[1] MLEV-17-BASED TWO-DIMENSIONAL HOMONUCLEAR MAGNETIZATION TRANSFER SPECTROSCOPY [J].

BAX, A ;

DAVIS, DG .

JOURNAL OF MAGNETIC RESONANCE, 1985, 65 (02) :355-360

[2] HYDROGEN BONDING AND CONFORMATION OF GLUCOSE AND POLYGLUCOSES IN DIMETHYLSULPHOXIDE SOLUTION [J].

CASU, B ;

REGGIANI, M ;

GALLO, GG ;

VIGEVANI, A .

TETRAHEDRON, 1966, 22 (09) :3061-+

[3]

CASU B, 1965, TETRAHEDRON LETT, P2253

[4] COMPOSITION, SEQUENCE, AND CONFORMATION OF POLYMERS AND OLIGOMERS OF GLUCOSE AS REVEALED BY C-13 NUCLEAR MAGNETIC-RESONANCE [J].

COLSON, P ;

JENNINGS, HJ ;

SMITH, ICP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (26) :8081-8087

[5] H-1-NMR CHEMICAL-SHIFT INFORMATION ON THE CONFORMATION OF THE GLYCOSIDIC BOND IN DISACCHARIDES [J].

DEBRUYN, A .

JOURNAL OF CARBOHYDRATE CHEMISTRY, 1991, 10 (02) :159-180

[6] RADIOFREQUENCY PULSE SEQUENCES WHICH COMPENSATE THEIR OWN IMPERFECTIONS [J].

FREEMAN, R ;

KEMPSELL, SP ;

LEVITT, MH .

JOURNAL OF MAGNETIC RESONANCE, 1980, 38 (03) :453-479

[7]

GAGNAIRE D, 1977, MAKROMOL CHEM, V178, P2321

[8] PREPARATION AND SOLUTION PROPERTIES OF PULLULAN FRACTIONS AS STANDARD SAMPLES FOR WATER-SOLUBLE POLYMERS [J].

KAWAHARA, K ;

OHTA, K ;

MIYAMOTO, H ;

NAKAMURA, S .

CARBOHYDRATE POLYMERS, 1984, 4 (05) :335-356

[9] NUCLEAR-MAGNETIC-RESONANCE STUDIES OF HOMOPOLYSACCHARIDES RELATED TO STARCH [J].

MCINTYRE, DD ;

VOGEL, HJ .

STARCH-STARKE, 1991, 43 (02) :69-76

[10]

MOLTENI L, 1979, DRUG CARRIERS BIOL M, P107

← 1 2 →