COLLISION-INDUCED DISSOCIATION AND CHARGE-TRANSFER REACTIONS OF SIFX+ (X = 1-4) - THERMOCHEMISTRY OF SIFX AND SIFX+

被引：92
作者：
FISHER, ER [1 ]
KICKEL, BL [1 ]
ARMENTROUT, PB [1 ]
机构：
[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 39期
关键词：
D O I：
10.1021/j100141a049
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Guided ion beam mass spectrometry is used to measure cross sections as a function of kinetic energy for interaction of SiF3+ (x = 1-4) ions with Xe. Energy dependences of the collision-induced dissociation cross sections are analyzed to yield the following 0 K bond dissociation energies (BDEs): D(SiF3+-F) = 0.85 +/- 0.16 eV, D(SiF2+-F) = 6.29 +/- 0.10 eV, D(SiF+-F) = 3.18 +/- 0.04 eV, and D(Si+-F) = 7.04 +/- 0.06 eV. The ionization energies, IE(SiF2) = 10.84 +/ -0.13 eV and IE(SiF3) = 9.03 +/- 0.05 eV, are also measured from analysis of endothermic charge transfer reactions. From these BDEs and IEs, previous results of Weber and Armentrout [J. Chem. Phys. 1988, 88, 68981, and work in the preceding paper, we derive heats of formation for the silicon fluoride cations and neutrals that provide a self-consistent set of thermochemical data for the silicon fluoride species. In some cases, the thermochemical values determined here are considerably different from available literature values but are in good agreement with theory. The differences are discussed in detail.
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页码：10204 / 10210
页数：7
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共 34 条
[21]   PHOTOINDUCED CHARGE-TRANSFER DISSOCIATION IN VAN-DER-WAALS COMPLEXES .4. NA(FCH3)(N) (N=1-4) [J].
POLANYI, JC ;
WANG, JX .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (37) :13691-13700
[22]   Photoinduced charge-transfer dissociation in van der Waals complexes. 4. Na . . . (FCH3)n (n = 1-4) [J].
J Phys Chem, 37 (13691)
[23]   SOLVATION OF TRANSITION-METAL IONS BY WATER - SEQUENTIAL BINDING-ENERGIES OF M(+)(H2O)(X), (X=1-4) FOR M=TI TO CU DETERMINED BY COLLISION-INDUCED DISSOCIATION [J].
DALLESKA, NF ;
HONMA, K ;
SUNDERLIN, LS ;
ARMENTROUT, PB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3519-3528
[24]   Experimental and theoretical studies of double minima in the potential-energy surfaces for HF-elimination reactions of SiFx(OH)y+ with H2O (x = 1-3, y = 0-2) via intramolecular H-atom transfer [J].
Ketvirtis, AE ;
Baranov, YI ;
Hopkinson, AC ;
Bohme, DK .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (07) :1162-1169
[25]   COLLISION-INDUCED DISSOCIATION STUDIES OF CO(CO)(X)(+), X=1-5 - SEQUENTIAL BOND-ENERGIES AND THE HEAT OF FORMATION OF CO(CO)(4) [J].
GOEBEL, S ;
HAYNES, CL ;
KHAN, FA ;
ARMENTROUT, PB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (26) :6994-7002
[26]   Absolute binding energies of lithium ions to short chain alcohols, CnH2n+O-2, n=1-4, determined by threshold collision-induced dissociation [J].
Rodgers, MT ;
Armentrout, PB .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (14) :2614-2625
[27]   Sequential bond energies of Ag+(H2O)n and Ag+(dimethyl ether)n, n=1-4, determined by threshold collision-induced dissociation [J].
Koizumi, H ;
Larson, M ;
Muntean, F ;
Armentrout, PB .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2003, 228 (2-3) :221-235
[28]   Guided Ion Beam Studies of the Collision-Induced Dissociation of CuOH+(H2O)n (n=1-4): Comprehensive Thermodynamic Data for Copper Ion Hydration [J].
Sweeney, Andrew F. ;
Armentrout, P. B. .
JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (44) :10210-10222
[29]   PRODUCTION OF HYDRATED METAL-IONS BY FAST ION OR ATOM BEAM SPUTTERING - COLLISION-INDUCED DISSOCIATION AND SUCCESSIVE HYDRATION ENERGIES OF GASEOUS CU+ WITH 1-4 WATER-MOLECULES [J].
MAGNERA, TF ;
DAVID, DE ;
STULIK, D ;
ORTH, RG ;
JONKMAN, HT ;
MICHL, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) :5036-5043
[30]   Collision-induced dissociation of [4Fe-4S] cubane cluster complexes:: [Fe4S4Cl4-x(SC2H5)x]2-/1- (x=0-4) [J].
Fu, You-Jun ;
Laskin, Julia ;
Wang, Lai-Sheng .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2006, 255 :102-110
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