1,4-ADDITION OF OPTICALLY-ACTIVE TRANSFERABLE LIGANDS FROM ORGANOCUPRATES - GENERATION AND REACTION OF HOMOCHIRAL ALPHA-ALKOXYORGANOCUPRATES

被引：25
作者：
LINDERMAN, RJ
GRIEDEL, BD
机构：
[1] Department of Chemistry, North Carolina State University, Raleigh
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 20期
关键词：
D O I：
10.1021/jo00307a004
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Homochiral higher order cyano a-alkoxy-organocuprate addition to ynoates and enones occurs with 0-97% retention of configuration; results that imply multiple reaction pathways may be operative in 1,4-ad. © 1990, American Chemical Society. All rights reserved.
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页码：5428 / 5430
页数：3
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