AN EFFICIENT INEXPENSIVE ELECTROCHEMICAL PREPARATION OF RUPPERTS REAGENT

被引：18

作者：

AYMARD, F

NEDELEC, JY

PERICHON, J

机构：

[1] Laboratoire d'Electrochimie, Catalyse et Synthèse Organique CNRS, 94320 Thiais, 2, Rue Henri Dunant

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)78453-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrochemical reduction of CF3Br in N,N-dimethylformamide (DMF) in the presence of Me(3)SiCl and a sacrificial aluminum anode provides Me(3)SiCF(3) in ca 90% faradaic yields.

引用

页码：8623 / 8624

页数：2

共 16 条

[1]

ANDRIEUX GP, 1990, J AM CHEM SOC, V108, P3509

[2] ELECTROSYNTHESIS, AN ALTERNATIVE FOR THE SYNTHESIS OF POLYCARBOSILANES [J].

BORDEAU, M ;

BIRAN, C ;

PONS, P ;

LEGER, MP ;

DUNOGUES, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 382 (03) :C21-C24

[3]

CHAUSSARD J, 1990, SYNTHESIS-STUTTGART, P369

[4]

KOLOMEITSEV AA, 1990, SYNTHESIS-STUTTGART, P1151

[5] PREPARATION OF TRIFLUOROMETHYL AND OTHER PERFLUOROALKYL COMPOUNDS WITH (PERFLUORALKYL)TRIMETHYLSILANES [J].

KRISHNAMURTI, R ;

BELLEW, DR ;

PRAKASH, GKS .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (03) :984-989

[6] ELECTROCHEMICAL CROSS-COUPLING OF ALKYL-HALIDES IN THE PRESENCE OF A SACRIFICIAL ANODE [J].

NEDELEC, JY ;

MOULOUD, HAH ;

FOLEST, JC ;

PERICHON, J .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (20) :4720-4724

[7]

PARATIAN JM, IN PRESS J ORGANOMET

[8] TETRAKIS(DIMETHYLAMINO)ETHYLENE TRIFLUOROIODOMETHANE, A SPECIFIC NOVEL TRIFLUOROMETHYLATING AGENT [J].

PAWELKE, G .

JOURNAL OF FLUORINE CHEMISTRY, 1989, 42 (03) :429-433

[9] ELECTROSYNTHESIS IN ORGANOSILICIC CHEMISTRY - PREPARATION OF PHENYL-TRIMETHYLSILANES AND BENZYL-TRIMETHYLSILANES [J].

PONS, P ;

BIRAN, C ;

BORDEAU, M ;

DUNOGUES, J ;

SIBILLE, S ;

PERICHON, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 321 (03) :C27-C29

[10] SYNTHETIC METHODS AND REACTIONS .141. FLUORIDE-INDUCED TRIFLUOROMETHYLATION OF CARBONYL-COMPOUNDS WITH TRIFLUOROMETHYLTRIMETHYLSILANE (TMS-CF3) - A TRIFLUOROMETHIDE EQUIVALENT [J].

PRAKASH, GKS ;

KRISHNAMURTI, R ;

OLAH, GA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) :393-395

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