SYNTHESIS AND STRUCTURE OF THE 1ST ALKYL-BRIDGED DOUBLE LADDER - [R(CL)SN(CH2)3SN(CL)R]O)4 (R = ME3SICH2)

被引：45

作者：

DAKTERNIEKS, D ^{[1
]}

JURKSCHAT, K ^{[1
]}

SCHOLLMEYER, D ^{[1
]}

WU, H ^{[1
]}

机构：

[1] JOHANNES GUTENBERG UNIV,INST ORGAN CHEM,W-6500 MAINZ,GERMANY

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 10期

关键词：

D O I：

10.1021/om00022a060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of ((t)Bu2SnO)3 with R(Cl2)Sn(CH2)3-Sn(Cl2)R (R = Me3SiCH2) gives an alkyl-bridged double ladder {[R(Cl)Sn(CH2)3Sn(Cl)R]O}4 which has been characterized in the solid state by X-ray crystallography and in solution by multinuclear NMR spectroscopy. The compound consists of two ladder-type layers which are bridged by four propyl chains. The structure observed in the solid state is retained in solution.

引用

页码：4121 / 4123

页数：3

共 7 条

[1] ASYMMETRIC DISTANNOXANE DIMERS [J].

GROSS, DC .

INORGANIC CHEMISTRY, 1989, 28 (12) :2355-2359

[2] MOSSBAUER RECOIL-FREE FRACTION AND STRUCTURE .2. DI-MU-3-OXO-BIS-(MU-DICHLORO)-BIS[MU-DIMETHYLTIN(IV)]-BIS-[CHLORODIMETHYLTIN(IV)], AND ITS ETHYL HOMOLOG [J].

HARRISON, PG ;

BEGLEY, MJ ;

MOLLOY, KC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 186 (02) :213-236

[3] DISTANNOXANE-CATALYZED ACETALIZATION OF CARBONYLS [J].

OTERA, J ;

DANOH, N ;

NOZAKI, H .

TETRAHEDRON, 1992, 48 (08) :1449-1456

[4] DISTANNOXANE-CATALYZED TRANSESTERIFICATION OF 1,N-DIOL DIACETATES - SELECTIVE TRANSFORMATION OF EITHER OF CHEMICALLY EQUIVALENT FUNCTIONAL-GROUPS [J].

OTERA, J ;

DANOH, N ;

NOZAKI, H .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (24) :1742-1745

[5] CRYSTAL-STRUCTURES OF ISOPROPYL-SUBSTITUTED AND "TRIMETHYLSILYLMETHYLENE-SUBSTITUTED CHLORO-HYDROXO-TETRAORGANYL-DISTANNOXANES [J].

PUFF, H ;

BUNG, I ;

FRIEDRICHS, E ;

JANSEN, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 254 (01) :23-32

[6] PENTA-COORDINATED MOLECULES .52. HYDROLYSIS PATHWAY LEADING TO THE FORMATION OF NOVEL OXO-BRIDGED AND HALO-BRIDGED TIN(IV) LADDER COMPOUNDS - THE MOLECULAR-STRUCTURE OF THE DIMERIC DISTANNOXANES [PH2(CL)SNOSNPH2(OH)]2.2(CH3)2CO AND [PH2(CL)SNOSNPH2(CL)]2 [J].

VOLLANO, JF ;

DAY, RO ;

HOLMES, RR .

ORGANOMETALLICS, 1984, 3 (05) :745-750

[7] SN-119 NMR SPECTROSCOPIC STUDY ON TETRAORGANODISTANNOXANES [J].

YANO, T ;

NAKASHIMA, K ;

OTERA, J ;

OKAWARA, R .

ORGANOMETALLICS, 1985, 4 (09) :1501-1503

← 1 →