NIOBIUM AND TANTALUM OXO COMPOUNDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF THE TETRANUCLEAR TANTALUM(V) OXO CLUSTER [(TAOCL2(O2CC6H4ME-P))4]

被引：14

作者：

BROWN, DA

ERRINGTON, W

WALLBRIDGE, MGH

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 07期

关键词：

D O I：

10.1039/dt9930001163

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Products from the reaction of MCl5 (M = Nb or Ta) with acids RCO2H (R = aryl) include the tetranuclear tantalum oxo cluster [{TaCl2(mu-O)(O2CC6H4Me-p)}4] containing a Ta4O4 core, dinuclear [(NbCl3-(O2CR)}2(mu-O)], and the monosubstituted [TaCl4(O2CR)].

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页码：1163 / 1164

页数：2

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