THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(2,2'-6',2''-TERPYRIDINE)MAGNESIUM PERCHLORATE MONOHYDRATE

被引：19
|
作者：
CONSTABLE, EC [1 ]
HEALY, J [1 ]
DREW, MGB [1 ]
机构：
[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND
来源：
POLYHEDRON | 1991年 / 10卷 / 16期
关键词：
D O I：
10.1016/S0277-5387(00)86050-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex [Mg(terpy)2][ClO4]2.H2O (terpy = 2,2':6',2"-terpyridine) may be prepared by the direct reaction of magnesium perchlorate with 2,2':6',2"-terpyridine. The magnesium is in a pseudo-octahedral environment very similar to that observed in transition metal bis-(2,2':6',2"-terpyridine) complexes. Crystallographic data: space group I4(1)/a, a = 12.531(13), c = 40.52(4) angstrom, V = 2912 angstrom 3, Z = 8.
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页码：1883 / 1887
页数：5
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