SOLVOLYSIS OF 9-ARYL-9-PENTACYCLO[4.3.0.02,4.03,8.05,7]-NONYL PARA-NITROBENZOATES - UNAMBIGUOUS EVIDENCE FOR PRESENCE OF CARBON PARTICIPATION BY APPLICATION OF TOOL OF INCREASING ELECTRON DEMAND

被引：43

作者：

BROWN, HC ^{[1
]}

RAVINDRANATHAN, M ^{[1
]}

机构：

[1] PURDUE UNIV,RICHARD B WETHERILL LAB,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1977年 / 99卷 / 01期

关键词：

D O I：

10.1021/ja00443a078

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：299 / 300

页数：2

共 16 条

[1]

Brown H. C, 1977, NONCLASSICAL ION PRO

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PETERS, EN .

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[3] SOLVOLYSIS OF 3-ARYL-3-NORTRICYCLYL P-NITROBENZOATES - EVIDENCE FOR MAJOR INCREASES IN ELECTRON SUPPLY BY CYCLOPROPYL GROUP WITH INCREASING ELECTRON DEMAND AT CATIONIC CENTER [J].

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[4] COMPARISON OF EFFECT OF SUBSTITUENTS AT 2-POSITION OF NORBORNYL SYSTEM WITH THEIR EFFECT IN REPRESENTATIVE SECONDARY ALIPHATIC + ALICYCLIC DERIVATIVES . EVIDENCE FOR ABSENCE OF NONCLASSICAL STABILIZATION OF NORBORNYL CATION [J].

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REI, MH .

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[5] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .11. RATES AND PRODUCTS OF SOLVOLYSIS OF 2-ARYL-2-NORBORNENYL-PARA-NITROBENZOATES AND 2-METHYL-2-NORBORNENYL PARA-NITROBENZOATES - EXO-ENDO RATE RATIO AS A FUNCTION OF INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

PETERS, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (26) :7442-7448

[6] STRUCTURAL EFFECTS IN SOLVOLYTIC REACTIONS .12. SOLVOLYSIS OF 2-ARYL-5-METHYL-2-NORBORNENYL-PARA-NITRO-BENZOATES AND 2,5-DIMETHYL-2-NORBORNENYL PARA-NITROBENZOATES - EVIDENCE FOR MAJOR PI PARTICIPATION REVEALED BY TOOL OF INCREASING ELECTRON DEMAND [J].

BROWN, HC ;

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RAVINDRANATHAN, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (26) :7449-7453

[7]

BROWN HC, 1975, J AM CHEMICAL SOC, V97, P7454

[8] REMOTE AND PROXIMATE SUBSTITUENT EFFECTS ON TRISHOMOCYCLOPROPENIUM ION FORMATION IN SOLVOLYSIS OF METHYL AND PHENYL SUBSTITUTED 9-PENTACYCLO[4.3.0.02,4.03,8.05,7]NONYL PARA-NITROBENZOATES [J].

COATES, RM ;

FRETZ, ER .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (01) :297-299

[9] GENERATION, NUCLEAR MAGNETIC-RESONANCE SPECTRA, AND STRUCTURE OF 9-PENTACYCLO[4.3.0.02,4.03,8.05,7]NONYL CATIONS [J].

COATES, RM ;

FRETZ, ER .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (09) :2538-2540

[10] CYCLOPROPANE PARTICIPATION AND DEGENERATE REARRANGEMENT IN SOLVOLYSIS OF 9-PENTACYCLO 4.3.0.02,4.03,8.05,7.NONYL PARA-NITROBENZOATE [J].

COATES, RM ;

KIRKPATR.JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (16) :4883-&

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