SOLUTION PROPERTIES OF ALKALI METAL PERFLUOROALKANOATES

被引:22
|
作者
MUZZALUPO, R
RANIERI, GA
LAMESA, C
机构
[1] UNIV ROME LA SAPIENZA,DEPT CHEM,I-00183 ROME,ITALY
[2] CALABRIA UNIV,DEPT CHEM,I-87030 RENDE,ITALY
关键词
COLLIGATIVE PROPERTIES; ELECTRICAL CONDUCTANCE; MICELLES; PERFLUORINATED SURFACTANTS; PHASE EQUILIBRIA; POTENTIOMETRY; SURFACE ACTIVITY; THERMODYNAMICS; VOLUMETRIC PROPERTIES;
D O I
10.1016/0927-7757(95)03268-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Solution properties of perfluorononanoic acid and of its alkali metal salts, volumetric, colligative, emf and electrical conductance experiments and were supported by studies on phase equilibria, performed in close proximity to the CMC. Thermodynamics of micelle formation has been analysed both in terms of a charged-phase model and according to an isodesmic multiple equilibrium approach for counterion effect on micellization and for the cooperativity of micellarization association, respectively.
引用
收藏
页码:327 / 336
页数:10
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