NICKELOCENE-MEDIATING SENSOR FOR HYDROGEN-PEROXIDE BASED ON BIOELECTROCATALYTIC REDUCTION OF HYDROGEN-PEROXIDE

被引：11
作者：
LIU, HY
QIAN, JH
LIU, YC
YU, TY
DENG, JQ
机构：
[1] SHANGHAI UNIV,DEPT CHEM & CHEM ENGN,SHANGHAI 200072,PEOPLES R CHINA
[2] FUDAN UNIV,DEPT CHEM,SHANGHAI 200433,PEOPLES R CHINA
[3] FUDAN UNIV,DEPT MACROMOLEC SCI,SHANGHAI 200433,PEOPLES R CHINA
来源：
ANALYTICAL PROCEEDINGS | 1995年 / 32卷 / 11期
关键词：
D O I：
10.1039/ai9953200475
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An amperometric H2O2 sensor using nickelocene as the electron transfer agent between immobilized horseradish peroxide and a glassy carbon electrode was fabricated. The sensor was highly sensitive to H2O2 with a detection limit of 5.0 X 10(-7) mol l(-1) H2O2 and a response time of less than 20 s. The effect of applied potential and temperature on the Michaelis-Menten constant was calculated and the influence of various experimental parameters such as pH, temperature and applied potential were explored for optimum analytical performance.
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页码：475 / 477
页数：3
相关论文
共 19 条
[1]   TTF-MODIFIED BIOSENSORS FOR HYDROGEN-PEROXIDE [J].
BIFULCO, L ;
CAMMAROTO, C ;
NEWMAN, JD ;
TURNER, APF .
ANALYTICAL LETTERS, 1994, 27 (08) :1443-1452
[2]   ELECTROCHEMICAL TRANSFORMATIONS OF PROTEINS ADSORBED AT CARBON ELECTRODES [J].
BOGDANOVSKAYA, VA ;
TARASEVICH, MR ;
HINTSCHE, R ;
SCHELLER, F .
BIOELECTROCHEMISTRY AND BIOENERGETICS, 1988, 19 (03) :581-584
[3]   KOHLRABI-BASED AMPEROMETRIC BIOSENSOR FOR HYDROGEN-PEROXIDE MEASUREMENT [J].
CHEN, L ;
LIN, MS ;
HARA, M ;
RECHNITZ, GA .
ANALYTICAL LETTERS, 1991, 24 (01) :1-14
[4]   OXIDATION OF PHENOL AND ITS REACTION-PRODUCT BY HORSERADISH-PEROXIDASE AND HYDROGEN-PEROXIDE [J].
DANNER, DJ ;
BRIGNAC, PJ ;
ARCENEAU.D ;
PATEL, V .
ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1973, 156 (02) :759-763
[5]  
DUNFORD HB, 1982, ADV INORG BIOCHEM, V4, P41
[6]  
DUNFORD HB, 1987, COORD CHEM, V19, P187
[7]   REACTIONS OF HORSERADISH-PEROXIDASE ON A PLATINUM CATHODE [J].
DURLIAT, H ;
COURTEIX, A ;
COMTAT, M .
BIOELECTROCHEMISTRY AND BIOENERGETICS, 1989, 22 (03) :197-209
[8]   A METHOD FOR ESTIMATION OF HYDROGEN-PEROXIDE BASED ON MEDIATED ELECTRON-TRANSFER REACTIONS OF PEROXIDASES AT ELECTRODES [J].
FREW, JE ;
HARMER, MA ;
HILL, HAO ;
LIBOR, SI .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 201 (01) :1-10
[9]  
GORTIER G, 1990, ANAL LETT, V23, P1607
[10]   MEDIATORLESS HORSERADISH-PEROXIDASE ENZYME ELECTRODES BASED ON ACTIVATED CARBON - POTENTIAL APPLICATION TO SPECIFIC BINDING ASSAY [J].
HO, WO ;
ATHEY, D ;
MCNEIL, CJ ;
HAGER, HJ ;
EVANS, GP ;
MULLEN, WH .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 351 (1-2) :185-197
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