FROM CYCLO-TE-8 TO TE(X)(N-)SHEETS - ARE NONCLASSICAL POLYTELLURIDES MORE CLASSICAL THAN WE THOUGHT

被引：33

作者：

KANATZIDIS, MG

机构：

[1] Department of Chemistry, Michigan State University, East Lansing, Michigan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 19期

关键词：

CHALCOGEN COMPOUNDS; POLYCHALCOGENIDES; TELLURIUM COMPOUNDS;

D O I：

10.1002/anie.199521091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The importance of exploratory synthesis in advancing inorganic chemistry is exemplified by the interesting results that have been obtained in polychalcogenide chemistry. Thus, for example, Te8 rings and planar [Te6] n3n− layers have been found in the solid‐state structure of Cs3Te22 [Angew. Chem. 1995, 107, 450]. The counterions, which appear to function as templates, strongly influence the formation and structure of the products. Is this a route to polychalcogenides with defined structural features and material properties? Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2109 / 2111

页数：3