ANIONIC VACANCY DISTRIBUTION IN REDUCED BARIUM LANTHANUM FERRITES - BAXLA1-XFEO3-X/2 (1/2 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 2/3)

被引:18
作者
GONZALEZCALBET, JM
PARRAS, M
VALLETREGI, M
GRENIER, JC
机构
[1] UNIV COMPLUTENSE,FAC FARM,DEPT QUIM INORGAN & BIOINORGAN,E-28040 MADRID,SPAIN
[2] UNIV BORDEAUX 1,CNRS,CHIM SOLIDE LAB,F-33405 TALENCE,FRANCE
关键词
D O I
10.1016/0022-4596(91)90247-F
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An electron diffraction and microscopy study of the BaxLa1-xFeO3- x 2 ( 1 2 ≤ x ≤ 2 3) samples to be formed by three-dimensional microdomains. The unit cell corresponding to each domain is related to the cubic perovskite structure by the expression ac × ac × 2ac, ac being the cubic perovskite unit cell parameter. A structural model in which octahedral and square pyramidal layers intergrow in an ordered way following the double axis is proposed. © 1991.
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页码:110 / 115
页数:6
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