Synthesis, Characterization and Applications in Catalysis of Polyoxometalate/Zeolite Composites

被引：22
作者：
Lefebvre, Frederic [1 ]
机构：
[1] Univ Lyon 1, C2P2, 43 Blvd 11 Novembre 1918, F-69626 Villeurbanne, France
来源：
INORGANICS | 2016年 / 4卷 / 02期
关键词：
polyoxometalates; zeolites; encapsulation; impregnation; synthesis; catalysis;
D O I：
10.3390/inorganics4020013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An overview of the synthesis, characterization and catalytic applications of polyoxometalates/zeolites composites is given. The solids obtained by direct synthesis of the polyoxometalate in the presence of the zeolite are first described with their applications in catalysis. Those obtained by a direct mixing of the two components are then reviewed. In all cases, special care is taken in the localization of the polyoxometalate, inside the zeolite crystal, in mesopores or at the external surface of the crystals, as deduced from the characterization methods.
引用
收藏
页数：24
相关论文
共 77 条
[1]  
ALBERTI A, 1972, TSCHERMAKS MINERAL P, V0018
[2]   Heteropolytungstic acid (H3PW12O40)-encapsulated into the titanium-exchanged HY (TiHY) zeolite:: a novel photocatalyst for photoreduction of methyl orange [J].
Anandan, S ;
Ryu, SY ;
Cho, WJ ;
Yoon, M .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 195 (1-2) :201-208
[3]   Heteropolyacid-encapsulated TiHY zeolite as an inorganic photosynthetic reaction center mimicking the plant systems [J].
Anandan, S ;
Yoon, M .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 160 (03) :181-184
[4]   The acid-catalysed reaction of α-pinene over molybdophosphoric acid immobilised in dense polymeric membranes [J].
Castanheiro, JE ;
Ramos, AM ;
Fonseca, I ;
Vital, J .
CATALYSIS TODAY, 2003, 82 (1-4) :187-193
[5]   Solar-based photoreduction of methyl orange using zeolite supported photocatalytic materials [J].
Chatti, Ravikrishna ;
Rayalu, Sadhana S. ;
Dubey, Nidhi ;
Labhsetwar, Nitin ;
Devotta, Sukumar .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (2-3) :180-190
[6]   Influence of zeolitic structure on photoreduction property and hydrogen evolution reaction [J].
Chatti, Ravikrishna V. ;
Dubey, Nidhi ;
Joshi, Meenal V. ;
Labhsetwar, Nitin K. ;
Joshi, P. N. ;
Rayalu, Sadhana S. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (05) :1911-1920
[7]   In situ nanocrystalline HZSM-5 zeolites encaged heteropoly acid H3PMo12O40 and Ni catalyst for hydroconversion of n-octane [J].
Chen, Lidong ;
Wang, Xiangsheng ;
Guo, Xinwen ;
Guo, Hongchen ;
Liu, Hai'ou ;
Chen, Yongying .
CHEMICAL ENGINEERING SCIENCE, 2007, 62 (16) :4469-4478
[8]   Polyoxometalate-based molecular materials [J].
Coronado, E ;
Gomez-Garcia, CJ .
CHEMICAL REVIEWS, 1998, 98 (01) :273-296
[9]   Structural effects of WO3 incorporation on USY zeolite and application to free fatty acids esterification [J].
Costa, Andreia A. ;
Braga, Patricia R. S. ;
de Macedo, Julio L. ;
Dias, Jose A. ;
Dias, Silvia C. L. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2012, 147 (01) :142-148
[10]   Synthesis of yolk-shell HPW@Hollow silicalite-1 for esterification reaction [J].
Dai, Chengyi ;
Zhang, Anfeng ;
Li, Junjie ;
Hou, Keke ;
Liu, Min ;
Song, Chunshan ;
Guo, Xinwen .
CHEMICAL COMMUNICATIONS, 2014, 50 (37) :4846-4848
12345678