VERSATILE REACTIONS OF ORGANOBORON POLYMERS PREPARED BY HYDROBORATION POLYMERIZATION

被引：11
作者：
CHUJO, Y
机构：
[1] Division of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto
来源：
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1994年 / A31卷 / 11期
关键词：
D O I：
10.1080/10601329408545874
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Hydroboration polymerization of dienes and thexylborane produces organoboron polymers, which can be regarded as a polymer homolog of trialkylboranes. In other words, the organoboron polymers obtained can be expected to be a novel type of reactive polymer. The present paper describes versatile reactions of organoboron polymers prepared by hydroboration polymerization. For example, reactions with carbon monoxide or with KCN were followed by oxidative treatment to produce the corresponding poly(alcohol)s or poly(ketone)s, respectively. The organoboron polymers were also reacted with bromopyridyl anion or with furyl anion to form cyano- or hydroxyl-containing polymers via ring-opening of pyridine or furan, respectively. Reductive treatment of the organoboron polymer gave the corresponding polymer after reductive cleavage of carbon-boron bonds.
引用
收藏
页码：1647 / 1655
页数：9
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