ON THE REACTIONS OF [RUCL2(PPH3)3] WITH THIA CROWN ETHERS - MOLECULAR-STRUCTURES OF [RUCL2(PPH3)([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) AND [RUCL(PPH3)([14]ANES4)CLO4 ([14]ANES4 = 1,4,8,11-TETRATHIACYCLOTETRADECANE)

被引：30

作者：

ALCOCK, NW

CANNADINE, JC

CLARK, GR

HILL, AF

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

[3] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 07期

关键词：

D O I：

10.1039/dt9930001131

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [RuCl2(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3) gives the neutral complex [RuCl2(PPh3)([9]aneS3)] while the same complex with 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4) followed by chloride-perchlorate metathesis provides the salt cis-[RuCl(PPh3)([14]aneS4)]ClO4. The structures of both complexes have been determined by X-ray crystallography.

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页码：1131 / 1135

页数：5

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