QUINONES .12. SYNTHESIS AND STRUCTURE OF A P-TERPHENOQUINONE AND PARAMAGNETIC SPECIES DERIVED THEREFROM

被引：29

作者：

BOLDT, P

BRUHNKE, D

GERSON, F

SCHOLZ, M

JONES, PG

BAR, F

机构：

[1] UNIV BASEL,INST PHYS CHEM,CH-4056 BASEL,SWITZERLAND

[2] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,W-3300 BRAUNSCHWEIG,GERMANY

[3] UNIV MARBURG,FACHBEREICH CHEM,W-3550 MARBURG,GERMANY

来源：

HELVETICA CHIMICA ACTA | 1993年 / 76卷 / 04期

关键词：

D O I：

10.1002/hlca.19930760430

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3,5,3'',5''-Tetra(tert-butyl)-p-terphenoquinone (12b) was synthesized and characterized by its spectroscopic and X-ray structural data. The ground state of 12b is singlet with a strong contribution of a biradical structure. Paramagnetic derivatives of 12b, such as the semiquinone radical anion (12b-) and its O-protonated form, the phenoxy radical (18), were studied by ESR and ENDOR spectroscopy.

引用

页码：1739 / 1751

页数：13

共 32 条

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