LIGAND REACTIVITY IN IRON(II) COMPLEXES OF 4'-(4'''-PYRIDYL)-2,2'/6',2''-TERPYRIDINE

被引：166

作者：

CONSTABLE, EC

THOMPSON, AMWC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 20期

关键词：

D O I：

10.1039/dt9920002947

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ligand 4'-(4'"-pyridyl)-2,2':6',2"-terpyridine (pyterpy) acts as a tridentate ligand in which the 4-pyridyl ring is not co-ordinated in the complex cation [Fe(pyterpy)2]2+; the non-co-ordinated ring reacts with electrophiles to give species in which the charge perturbations are localised to a '4,4'-bipyridyl' fragment.

引用

收藏

页码：2947 / 2950

页数：4

相关论文

共 16 条

[1] LIGAND REACTIVITY IN COORDINATION-COMPOUNDS - A MOLECULAR-ORBITAL INVESTIGATION OF THE QUATERNIZATION-COORDINATION ANALOGY [J].

CONSTABLE, EC ;

HOUSECROFT, CE .

TRANSITION METAL CHEMISTRY, 1988, 13 (01) :19-21

[2] THE COORDINATION CHEMISTRY OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE - THE SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURES OF 4'-PHENYL-2,2'-6',2''-TERPYRIDINE AND BIS(4'-PHENYL-2,2'-6',2''-TERPYRIDINE)NICKEL(II) CHLORIDE DECAHYDRATE [J].

CONSTABLE, EC ;

LEWIS, J ;

LIPTROT, MC ;

RAITHBY, PR .

INORGANICA CHIMICA ACTA, 1990, 178 (01) :47-54

[3] LIGAND REACTIVITY IN 2,2'-BIPYRIDINE COMPLEXES - CHARGE EFFECTS UPON REACTIONS WITH BASE [J].

CONSTABLE, EC .

POLYHEDRON, 1989, 8 (01) :83-86

[4] LIGAND REACTIVITY IN POLYPYRIDINE COMPLEXES - THE DEUTERIATION OF THE BIS(2,2'-6',2''-TERPYRIDINE)RUTHENIUM(II) CATION [J].

CONSTABLE, EC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (12) :2687-2689

[5] A CONVENIENT, HIGH-YIELD SYNTHESIS OF 2,2'-6',2'-TERPYRIDINE AND ITS IRON(II) COMPLEX [J].

CONSTABLE, EC ;

WARD, MD ;

CORR, S .

INORGANICA CHIMICA ACTA, 1988, 141 (02) :201-203

[6] NEO-CLASSICAL COORDINATION CHEMISTRY - PRINCIPLES OF LIGAND REACTIVITY IN COORDINATION-COMPOUNDS [J].

CONSTABLE, EC .

INORGANICA CHIMICA ACTA, 1988, 145 (01) :49-51

[7] THE ALKYLATION OF SOME RUTHENIUM(II) COMPLEXES OF AMBIDENT HETEROCYCLIC LIGANDS [J].

CONSTABLE, EC ;

LEWIS, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 254 (01) :105-110

[8] THE ELECTRONIC-STRUCTURE OF SOME RUTHENIUM(II) COMPLEXES RELATED TO [RU(BIPY)3]2+ - AN INVESTIGATION OF THE STEPWISE REPLACEMENT OF N,N-DONORS BY C,N-DONORS [J].

CONSTABLE, EC ;

HOUSECROFT, CE .

POLYHEDRON, 1990, 9 (15-16) :1939-1947

[9] LIGAND REACTIVITY IN COORDINATED HETEROCYCLES - A COMMENT [J].

CONSTABLE, EC .

INORGANICA CHIMICA ACTA, 1986, 117 (02) :L33-L34

[10] A DEUTERIUM-EXCHANGE REACTION OF THE "TRIS-(2,2'-BIPYRIDINE)RUTHENIUM(II) CATION - EVIDENCE FOR THE ACIDITY OF THE 3,3'-PROTONS [J].

CONSTABLE, EC ;

SEDDON, KR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (01) :34-36