KINETICS AND MECHANISM OF OXIDATION OF ACETANILIDE BY QUINQUEVALENT VANADIUM IN ACID-MEDIUM

被引：4
|
作者：
GUPTA, R [1 ]
机构：
[1] GOVT SCI COLL,CHEM LABS,REWA 486001,INDIA
来源：
MONATSHEFTE FUR CHEMIE | 1990年 / 121卷 / 8-9期
关键词：
Acetanilide; Kinetics; Mechanism; Oxidation; Vanadium(V);
D O I：
10.1007/BF00809758
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of the oxidation of acetanilide with vanadium(V) in sulphuric acid medium at constant ionic strength has been studied. The reaction is first order with oxidant. The order of reaction in acetanilide varies from one to zero. The reaction follows an acid catalyzed independent path, exhibiting square dependence in H+. A Bunnett plot indicates that the water acts as a nucleophile. The thermodynamic parameters have been computed. A probable reaction mechanism and rate law consistent with these data are given. © 1990 Springer-Verlag.
引用
收藏
页码：571 / 576
页数：6
相关论文
共 50 条
  • [31] KINETICS OF OXIDATION OF ACETALDEHYDE BY CHLORAMINE-T IN ACID-MEDIUM
    MAHADEVAPPA, DS
    JADHAV, MB
    NAIDU, HMK
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1981, 58 (05) : 454 - 455
  • [32] OXIDATION-KINETICS OF THIOSALICYLIC ACID BY FERRICYANIDE ION IN ACID-MEDIUM
    PANPALIA, SS
    MEHROTRA, RN
    KAPOOR, RC
    INDIAN JOURNAL OF CHEMISTRY, 1974, 12 (11): : 1166 - 1170
  • [33] KINETICS OF OXIDATION OF GLYCYLGLYCINE BY BROMAMINE-T IN ACID-MEDIUM
    IYENGAR, TA
    MAHADEVAPPA, DS
    PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1993, 105 (01): : 63 - 70
  • [34] KINETICS OF HEXOSE OXIDATION BY SILVER AND MERCURY IONS IN ACID-MEDIUM
    KRUPENSKII, VI
    ZHURNAL OBSHCHEI KHIMII, 1984, 54 (11): : 2579 - 2582
  • [35] KINETICS AND MECHANISM OF THE OXIDATION OF SOME HETEROCYCLIC SECONDARY ALCOHOLS BY N-BROMOACETAMIDE IN ACID-MEDIUM
    JAMBULINGAM, M
    NANJAPPAN, P
    NATARAJAN, K
    NAGALINGAM, J
    PALANISWAMY, M
    SIVAKUMAR, N
    PREKUMAR, V
    RAMARAJAN, K
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (11): : 1699 - 1702
  • [36] KINETICS OF OXIDATION OF PYRIDOXINE BY CHLORAMINE-T IN ACID-MEDIUM
    JAYARAM, B
    GOWDA, NMM
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (12) : 4395 - 4399
  • [37] KINETICS OF ALDOSE OXIDATION BY CU(II) IONS IN AN ACID-MEDIUM
    KRUPENSKII, VI
    ZHURNAL OBSHCHEI KHIMII, 1983, 53 (02): : 430 - 433
  • [38] KINETICS OF OXIDATION OF ACETOPHENONE BY CHLORAMINE-T IN ACID-MEDIUM
    SINGH, KJ
    RAINA, N
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1977, 54 (05) : 482 - 484
  • [39] THE KINETICS OF OXIDATION OF D (+) GLUCOSE BY POTASSIUM BROMATE IN ACID-MEDIUM
    SHUKLA, SN
    BAJPAI, CD
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1980, 57 (08) : 852 - 854
  • [40] KINETICS AND MECHANISM OF THE OXIDATION OF ALIPHATIC-ALCOHOLS BY SODIUM N-CHLOROBENZENESULPHONAMIDE IN ACID-MEDIUM
    MUKHERJEE, J
    BANERJI, KK
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1981, 20 (04): : 394 - 395
12345