KINETICS AND MECHANISM OF OXIDATION OF ACETANILIDE BY QUINQUEVALENT VANADIUM IN ACID-MEDIUM

被引：4

作者：

GUPTA, R ^{[1
]}

机构：

[1] GOVT SCI COLL,CHEM LABS,REWA 486001,INDIA

来源：

MONATSHEFTE FUR CHEMIE | 1990年 / 121卷 / 8-9期

关键词：

Acetanilide; Kinetics; Mechanism; Oxidation; Vanadium(V);

D O I：

10.1007/BF00809758

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the oxidation of acetanilide with vanadium(V) in sulphuric acid medium at constant ionic strength has been studied. The reaction is first order with oxidant. The order of reaction in acetanilide varies from one to zero. The reaction follows an acid catalyzed independent path, exhibiting square dependence in H+. A Bunnett plot indicates that the water acts as a nucleophile. The thermodynamic parameters have been computed. A probable reaction mechanism and rate law consistent with these data are given. © 1990 Springer-Verlag.

引用

页码：571 / 576

页数：6

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